The invention relates to a method for preparing a TiO2
composite film on a surface of a glass substrate. The method comprises the following steps: soaking the glass substrate in a solution containing H2SO4 and H2O2 according to volume ratio of 70 to 30, treating the glass substrate for 1 hour at a temperature of 90 DEG C, after cleaning and
drying the glass substrate, soaking the glass substrate in a
benzene solution containing hydrosulfuryl
silane the concentration of which is between 0.1 and 2.0 mmol per
liter, standing for 6 to 8 hours, taking out and washing the glass substrate,
drying the glass substrate by blowing
nitrogen, placing the glass substrate in 30-60
mass percent
nitric acid, reacting for 1 hour at a temperature of between 50 and 80 DEG C, taking out and washing the glass substrate, and obtaining the glass substrate the surface of which is adhered with a sulfonic
silane film; and placing the substrate in TiO2 suspension, standing for 4 to 20 hours at a temperature of between 20 and 80 DEG C; and taking out and washing the glass substrate by a large amount of deionized water,
drying the washed glass substrate by blowing the
nitrogen, and obtaining the glass substrate the surface of which is deposited with a modified TiO2
composite film. The method has short film forming period, can reduce
frictional coefficient from 0.8 to 0.1 without a film, and has quite remarkable antifriction function.