The invention discloses an electronic injection flash boiler for supercritical pyrolysis gas. The electronic injection flash boiler for the supercritical pyrolysis gas is composed of a fused salt adding pipe, a fused salt groove, a fused salt discharge pipe, a heat-insulation layer, a combustion cavity, a smoke pipe, a smoke cavity, a combustor, a waste heat recovery water tank, a water outlet pipe, a high-pressure plunger pump, a high-pressure spraying device, a steam generator, a steam coiled pipe, a steam groove, a steam distribution cylinder, a smoke discharge pipe, a water inlet pipe, a first smoke groove, a second smoke groove, a third smoke groove, an air pipe, a water groove, a steam turbine, a power generator, a first electric heater, a second electric heater, a solid material conveyer, a liquid material conveyer, a steam collision substance decomposition coiled pipe, a vertical separation tower, a horizontal decomposition chamber, a circulation water pump and a cooling tower.The invention provides a substance thermal decomposition and separation device which is simple in structure, efficient and energy-saving, high in heat conversion efficiency, large in heat exchange area, complete in substance classification, adequate in decomposition, clear in separation, high in collection speed, convenient to operate, capable of realizing waste heat utilization, and free from emission.