The invention discloses a
metal organic formwork
corrosion inhibitor-hydrogel compound with a Fe2+ response characteristic, and a preparation method and application thereof. The
metal organic formworkcorrosion inhibitor-hydrogel compound is composed of
polyvinyl alcohol hydrogel and a
copper-based
carboxylic acid metal organic formwork doped in the hydrogel and encapsulated with a 1H-1,2,4-
triazole-3-
thiol corrosion inhibitor. The preparation method includes the steps that firstly, in-situ encapsulation of a
corrosion inhibitor guest in a metal organic formwork encapsulation solution is achieved through a one-pot synthesis method, then an encapsulation precursor is doped into the
polyvinyl alcohol hydrogel, the growth rate of a
nanoshell is decreased through the coordination effect of a hydrogel
monomer and a metal center in the metal organic formwork, thus the integration of a formwork structure is improved, high-capacity encapsulation of the
corrosion inhibitor is achieved finally,and the high-load hydrogel compound of the metal organic formwork encapsulation
corrosion inhibitor is formed. The corrosion inhibition compound can be applied to a
seawater corrosion engineering structure, a main characteristic product of
carbon steel corrosion in a
seawater environment is free
divalent iron ions, the ions are replaced with the center of cetyl trimethyl
ammonium positive ions ofthe metal organic formwork, thus the outer surface hole
diameter of a frame can be enlarged, the
corrosion inhibitor encapsulated inside is released, and target protection of the corrosion area is achieved. By adopting a corrosion inhibition
system, the targeting ability is high, the efficient and durable effects are achieved,
cost performance is high, and significant application value and broad market prospects are achieved.