The invention belongs to the field of organic
material chemistry, and discloses a preparation method and properties of X-type rigid bridging
pyrene-
triphenylene quadruplex
discotic liquid crystal, and the X-type rigid bridging
pyrene-
triphenylene quadruplex
discotic liquid crystal has a structure as shown in a general formula I. The compound shown in the general formula I is mainly synthesized from a
pyrene tetraborate compound and a monobromobenzophenanthrene derivative through Suzuki-Miyaura cross
coupling, the reaction condition is mild, the steps are simple and efficient, and the atom
utilization rate is high. The compound has thermotropic
liquid crystal property, the intermediate phase is a columnar phase (Col) and a nematic phase (N), the
melting point and clearing point of the
discotic liquid crystal compound are improved by introducing a rigid ring serving as a bridge, the temperature range of the
liquid crystal intermediate phase is widened, the variety is enriched, and meanwhile, the compound has good
fluorescence emission and
quantum yield in a solution and a film aggregation state. The maximum
responsivity of the organic
photoconductive detector prepared by taking the Py-TP6 as the
absorption layer is 1.25 A / W (the power is 1.18 mW / cm < 2 >), 2.40 A / W (the power is 1.52 mW / cm < 2 >) and 9.23 A / W (the power is 0.63 mW / cm < 2 >) at the
wavelength of 405 nm, 532 nm and 650 nm respectively.