The invention provides a tridentate [ONO]
tungsten coordination compound and optical application thereof, and the tridentate [ONO]
tungsten coordination compound is divided into but not limited to three structures, namely a structure I, a structure II and a structure III, the synthesis method of the tridentate
tungsten coordination compound mainly comprises the following steps: mixing different equal amounts of tridentate [ONO]
phenol imine compounds serving as ligands with dichlorotungsten dioxide and 2.2-3 times of
pyridine, and carrying out
reflux reaction at 115-135 DEG C for at least 24 hours by taking methylbenzene as a
solvent, so as to obtain the tridentate [ONO] tungsten coordination compound. The tridentate [ONO] tungsten coordination compound is synthesized by using different tridentate [ONO]
phenol imine compounds as ligands, tungsten dioxide dichloride and
pyridine, the ligands are subjected to configuration torsion after optical excitation, and when
metal tungsten is added to form a
metal-ligand coordination bond, the configuration torsion of the ligands is limited, the energy relaxation is reduced, the ligand
red shift is obvious, and the light is enhancedl; the tridentate [ONO] tungsten coordination compound can be used as a light-emitting material; and meanwhile, the synthesized complex has
chirality, so that the synthesized complex can be used as a
circular polarization luminescent material for practical application.