The invention discloses a non-contact laser ultrasonic nondestructive testing system and method applicable to any curved surface. The system comprises a light source, a first reflector, a second reflector, an optical medium, a continuous laser device, a beam splitter, a photoelectric detector, a mechanical arm, a controller, a signal modulating device, a data collecting card and a computer. The method comprises that the light source emits pulse laser onto the surface of an object to be detected, ultrasonic waves produced based on the thermo-elastic mechanism penetrate through the optical medium between the two reflectors to cause change in the intensity of transmitted and reflected laser, the photoelectric detector measures the intensity of the laser and outputs signals, with assistance ofa mechanical scanning unit, scanning over of a region of interest is completed, during scanning, the output signals and scanning position data are synchronously collected, and through data treatment,three-dimensional distribution information of defects can be acquired. The non-contact laser ultrasonic nondestructive testing system and method applicable to any curved surface achieves ultrasonic wave excitation and detection with laser, thereby adapting to complex detecting conditions and achieving rapid, accurate and automatic non-destructive detection of defects of any curved surface part.