The invention discloses an environment-friendly detection water sample storage device convenient to take. The environment-friendly detection water sample storage device convenient to take comprises astorage box, balls, a sample storage pipe and a valve plate, a refrigeration column is installed in the storage box, a storage sleeve is arranged on the outer side of the refrigeration column, the storage sleeve is also located in the storage box, the balls are arranged between the storage sleeve and the refrigeration column, the storage sleeve is connected with the refrigeration column through the balls, an inserting rod is installed at the upper end of the valve plate, a reset spring is arranged on the outer side of a supporting rod, the reset spring is located on the inner side of a limiting groove, and the supporting rod is connected with the valve plate through the reset spring. According to the environment-friendly detection water sample storage device convenient to take, a water sample can be put into the sample storage pipe to be inserted into a storage cavity to be stored, meanwhile, liquid nitrogen can be injected into the hollow refrigeration column to control the temperature in the storage box and the storage sleeve, then the water sample can be conveniently stored at a low temperature, and the condition of high-temperature evaporation of the water sample is avoided.