The invention discloses a colorless and transparent polyimide film, the molecular structural formula as shown in a formula I. A preparation method of the polyimide film comprises the following steps: polymerizing a fluorine-containing diamine monomer and a dianhydride monomer which have same moles in a polar aprotic solvent to produce a colorless and transparent poly(amicacid) solution, carrying out dehydration and ring closing on the colorless and transparent poly(amicacid) solution by using a hot imidization method or a chemical imidization method to produce the colorless and transparent polyimide film, wherein the dianhydride monomer is one or two of compounds selected from bicyclic (3,3,0)octane-2,4,6,7-tetracid dihydride or bicyclic (4,3,0)nonane-3,4,7,9-tetracid dihydride, the fluorine-containing diamine monomer is one or a combination of two of compounds selected from 4,4'-di(4-amino-2-trifluoromethylphenoxy)diphenyl ether, 4,4'-di(4-amino-2- trifluoromethylphenoxy) biphenyl and 2,2'-di(4-(4-amino-2- trifluoromethylphenoxy) phenyl) hexafluoropropane. The colorless and transparent polyimide film produced by using the alicyclic type dianhydride monomer has excellent performances such as good heat resistance, good solubility and high light transmittance.