The invention discloses a
polymer composite film and a preparation method thereof, and a
lithium ion battery comprising the
polymer composite film. The
polymer composite film comprises a polymer basefilm, which comprises a first surface and a second surface, wherein the first surface and the second surface are oppositely arranged, the polymer composite film further comprises a first
ceramic layer, a first heat-resistant
fiber layer and a first adhesion layer, the first
ceramic layer, the first heat-resistant
fiber layer and the first adhesion layer are sequentially arranged on the first surface of the polymer base film from inside to outside, the materials of the first heat-resistant
fiber layer simultaneously contain a first
macromolecule material and a second
macromolecule material, thefirst
macromolecule material is a heat-resistant macromolecule material with a
melting point of more than 180 DEG C, the
melting point of the second macromolecule material is lower than the
melting point of the first macromolecule material, the liquid
absorption rate of the second macromolecule material in a 25 DEG C
electrolyte is more than 40%, and the error is + / -5%. According to the present invention, by simultaneously using the first macromolecule material and the second macromolecule material, the high temperature stability and the
mechanical property under the high temperature condition can be easily improved.