The invention discloses a graphene fiber modified nano adsorbing material and a preparation method. The nano adsorbing material comprises organic silicon resin, an organic solvent, glass beads, titanium dioxide, quartz sand, silicon carbide micro powder, nano cerium oxide, oxalic acid polyesters, light calcium carbonate, high-water-retention resin polyvinyl alcohol, a dispersing agent, a thickening agent, a brightening agent, zinc sulfide, foamed aluminum, hydroxypropyl methyl cellulose, nano silica, an adhesive, cobalt naphthenate, molybdenum, nickel, propylene glycol and chromium. Due to the fact that molecules of chitosan has positive charges, bacteria with negative charges can be adsorbed, and the material has a sterilization function; structurally, fibrous membrane layers with different diameters and pores are prepared, and in combination with nano graphene between the layers, the porosity and specific surface area of a composite adsorption membrane are improved, and effects are enhanced; by the adoption of pitch-based carbon fibers, the mechanical properties of the material are enhanced, and harmful gas and dust substances in tail gas can be greatly adsorbed and removed.