The invention discloses an electrode frame structure of single batteries in a redox flow battery as well as the single battery and an electric pile, wherein the structure of the electric pile is formed by sequentially combining a cover plate, an end plate, a collector plate, a plurality of single batteries, a collector plate, a shunt plate, a collector plate, a plurality of single batteries, a collector plate, an end plate and a cover plate, and the two cover plates arranged at the two ends are respectively fastened by a fastener in a mechanical way; an electrode frame assembly comprises a film frame and an electrode frame which are sealed by a sealing strip or a buckle, or in a combining way; the physical structure stability of an ionic membrane is greatly improved by the structure of the film frame in the assembly process, the electric pile is convenient to assemble, and the stability of an electric pile module is improved; due to the design that the film frame is integrated with the electrode frame, the distribution of a flow field is optimized, the contact resistance between the membrane and an electrode is reduced, and the battery efficiency is improved. The electric pile is formed by N half piles, so that the power of the single pile can be improved, the distribution uniformity of electrolyte of a main pipeline can be effectively guaranteed, the effects of pre-assembling and pre-checking the half piles for the assembly of the electric pile can be achieved, and the electric pile is convenient to maintain.