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35results about How to "Long reaction time" patented technology

Certain polyester compositions which comprise cyclohexanedimethanol, moderate cyclobutanediol, cyclohexanedimethanol, and high trans cyclohexanedicarboxylic acid

Described as one aspect of the invention are polyester compositions A polyester composition comprising at least one polyester which comprises:
    • (A) a dicarboxylic acid component comprising:
      • i) 70 to 100 mole % of cyclohexanedicarboxylic acid residues or an ester thereof comprising:
        • (a) 80 to 99 mole % trans-cyclohexanedicarboxylic acid residues or an ester thereof; and
        • (b) 1 to 20 mole % cis-cyclohexanedicarboxylic acid residues or an ester thereof;
      • ii) 0 to 30 mole % of aliphatic dicarboxylic acid residues, other than cyclohexanedicarboxylic acid residues, having up to 16 carbon atoms or esters thereof, other than cyclohexanedicarboxylic acid residues; and
      • iii) 0 to 10 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and
    • (B) a glycol component comprising:
      • i) 5 to 35 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and
      • ii) 65 to 95 mole % of 1,4-cyclohexanedimethanol residues, 1,3-cyclohexanedimethanol residues, 1,2-cyclohexanedimethanol residues or esters thereof or mixtures thereof,
wherein the total mole % of said dicarboxylic acid component is equal to 100 mole %;
the total mole % of said glycol component is equal to 100 mole %;
wherein the inherent viscosity of said polyester is from 0.35 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C.; and wherein said polyester has a Tg of from 66 to 120° C. The polyesters may be manufactured into articles.
Owner:EASTMAN CHEM CO

Clean preparation method of magnalium based laminated composite hydroxide

The invention provides a clean preparation method of a magnalium based laminated composite hydroxide. The method uses magnesium hydroxide, magnesium oxide, pseudo boehmite, inorganic acid and a material containing functional anions as raw materials, uses magnesium chloride or magnesium nitrate as a circulation medium, and uses the property of peptization under acidic condition of boehmite to improve the reaction activity of pseudoboehmite; the concentration of magnesium ions in solution is increased by using magnesium chloride or magnesium nitrate. The method accelerates the formation rate of laminated composite hydroxide, promotes the dissolution of magnesium hydroxide and magnesium oxide, shortens the reaction time, overcomes the defects of high reaction temperature and long time consumption in hydrothermal method for synthesis of laminated composite hydroxide, and can rapidly prepare magnalium based laminated composite hydroxide under mild conditions. Magnesium chloride and magnesium nitrate can be recycled; and the preparation process has no waste discharge, and is green and environment-friendly. The method has the advantages of abundant raw materials, low cost, simple preparation process, mild reaction conditions, and easiness to industrial production.
Owner:BEIJING UNIV OF CHEM TECH

A clean preparation method of magnesium-aluminum-based layered composite hydroxide

A clean preparation method of magnesium-aluminum-based layered composite hydroxide. The present invention uses magnesium hydroxide and magnesium oxide, pseudo-boehmite, inorganic strong acid, and functional anion-containing substances as raw materials, uses magnesium chloride or magnesium nitrate as a circulating medium, and utilizes the property that pseudo-boehmite can be peptized under acidic conditions Improve the reactivity of pseudo-boehmite, use magnesium chloride or magnesium nitrate to increase the concentration of magnesium ions in the solution, accelerate the formation rate of layered composite hydroxide and promote the dissolution of magnesium hydroxide and magnesium oxide, shorten the reaction time, overcome the water The preparation of layered composite hydroxide by thermal method has the disadvantages of high reaction temperature and long time consumption, but magnesium-aluminum-based layered composite hydroxide can be rapidly prepared under mild conditions. Magnesium chloride and magnesium nitrate can be recycled, and there is no waste discharge in the preparation process, which is green and environmentally friendly. The method has the advantages of rich source of raw materials, low price, simple preparation process, mild reaction conditions, easy industrial production and the like.
Owner:BEIJING UNIV OF CHEM TECH

A Method for Enzymatic Resolution of Chiral Substances

The invention belongs to the field of bioengineering and food technology, and discloses a method for enzymatic resolution of chiral substances, including the following steps: (1) preparing an enzyme solution with a lipase concentration of 1-3000 U/mL, and adding a soluble salt, a hydrophilic solvent and a hydrophobic solvent to the enzyme solution to form a three-liquid phase system; the hydrophobic solvent contains esters or amide compounds composed of racemic chiral compounds; (2) subjecting the three-liquid phase system to enzyme-catalyzed reaction under stirring condition; after the reaction is completed, standing or centrifuging the three-liquid phase system to divide it into three layers, which are a upper liquid layer, a middle liquid layer and a lower liquid layer from top to bottom. The optically pure chiral product after hydrolysis is mainly rich in the middle liquid layer or the lower liquid layer, while the upper liquid layer product is another ester or amide product containing an optically pure chiral product. The method has the advantages of low energy consumption, high raw material utilization rate, and mild reaction conditions, and solves the problems of low chiral resolution efficiency, poor chiral selectivity, low recovery rate, and difficulty in industrialization in the existing enzymatic method.
Owner:SOUTH CHINA UNIV OF TECH
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