49 results about "Zirconium compounds" patented technology

The invention discloses a polyamide composite material as well as a preparation method and application thereof, and relates to the technical field of high polymer materials. The invention provides a polyamide composite material. The polyamide composite material comprises the following components in parts by weight: 30-60 parts of polyamide resin, 12-32 parts of a brominated flame retardant, 4-12 parts of organic phosphinate, 0.1-1 part of a zirconium compound, 0-50 parts of glass fibers, 0-3 parts of an antioxidant and 0-3 parts of a lubricant, and the particle size D50 of the zirconium compound is 0.08-2 [mu] m. According to the antimony-free halogen-containing flame-retardant polyamide composite material provided by the invention, a traditional bromine-antimony flame-retardant system is synergistically replaced by the organic phosphinate and the zirconium compound, and the prepared polyamide composite material has excellent mechanical properties, flame retardance and thermal decomposition stability.

The invention relates to the technical field of cable materials, and particularly discloses a low-smoke halogen-free flame-retardant cable material and a preparation method thereof. The low-smoke halogen-free flame-retardant cable material is prepared from 100 parts of polyolefin blended resin, 10 to 20 parts of polyphenyl ether, 3 to 8 parts of glycidyl methacrylate grafted POE, 1 to 3 parts of hyperbranched polyesteramide, 50 to 80 parts of a flame retardant, 5 to 15 parts of silicone powder, 0.5 to 1.5 parts of an antioxidant and 0.05 to 0.2 part of an organic zirconium compound. The preparation method comprises the following steps: uniformly mixing the raw materials to obtain a mixture; and adding the mixture into a twin-screw extruder, carrying out melt extrusion by the twin-screw extruder, cooling, granulating, and drying to obtain the low-smoke halogen-free flame-retardant cable material. The mechanical property and temperature resistance of the low-smoke halogen-free flame-retardant cable material can be improved.

The application relates to the technical field of textiles, and particularly discloses a plastic fiber deodorizing master batch and a preparation method thereof.A plastic fiber deodorizing master batch, according to mass percentage, raw materials include 50-87% plastic chips, 5-20% zinc oxide, 5-20% zirconium compound composite powder and 3-10% composite dispersant, the zirconium compound composite powder includes zirconium hydroxide and layered zirconium phosphate.The plastic fiber deodorizing master batch can efficiently adsorb and decompose various odors such as ammonia, acetic acid, isoamyl acid and nonenal, has a wider deodorization spectrum, a higher elimination rate and stronger deodorization durability.

The application discloses a high-nickel positive electrode material and a preparation method and application thereof, and belongs to the technical field of new energy sources. x Co y M z M´ w O2 and a porous base material and a gap-filling substance, wherein 0.80<=x<=0.98, 0.02<=y<=0.20, 0<=z<=0.06, 0<w<=0.02; x+y+z+w=1; M is at least one of Mn and Al, M´ is at least one of Y, Sr, La, B, Mg and Ti; the gap-filling substance exists in the inside of the pores and comprises a sintered product derived from an additive B, the additive B comprises a zirconium-containing compound and at least one of a tungsten-containing compound, an antimony-containing compound and a bismuth-containing compound. The high-nickel positive electrode material has excellent long cycle performance and rate performance. The application further provides a preparation method and application of the high-nickel positive electrode material.

The invention discloses a composite ceramic material as well as a preparation method and application thereof. The composite ceramic material comprises an inner core and a shell layer, the shell layer coats at least part of the surface of the inner core; the inner core is prepared from raw materials including aluminum oxide, first YSZ ceramic and second YSZ ceramic; the shell layer is prepared from raw materials including a zirconium compound and a first binder. The first YSZ ceramic with the high yttrium content and the second YSZ ceramic with the low yttrium content are matched, a toughening synergistic mechanism combining a metastable region with non-uniform grain boundary Y enrichment is constructed, and compared with a traditional uniform doping method, the forming effect of the composite ceramic material can be remarkably improved; the fracture toughness and the bending strength are effectively improved on the premise that the sintering density and the hardness are not obviously influenced; and moreover, by forming the core-shell structure, the microstructure can be optimized, and synergistic improvement of strength and toughness is macroscopically realized.

The invention discloses an N-alkanoyl alkylamide hafnium / zirconium mixed complex as well as a preparation method and application thereof. Under the protection of inert gas, quantitative N-alkanoyl alkylamide and a tetra (diamine) hafnium / zirconium compound are added into an anhydrous solvent; adding an anhydrous solvent, reacting for a period of time, filtering, and removing the solvent and byproducts from the filtrate by reduced pressure distillation to obtain a white solid; and recrystallizing and sublimating the white solid to obtain the target metal complex. The precursor of the complex is a mononuclear compound formed by the ligand with large steric hindrance, and has good volatility and appropriate thermal stability, the synthesized product has small pollution to the substrate, the synthesis method is simple and convenient, the process operation is simple, the yield is high, the cost is low, and the complex has good application value in the field of preparation of high-K materials.

The present application belongs to the technical field of semiconductors, and particularly relates to a zirconium compound, a precursor composition containing the same, a thin film and a preparation method thereof. The zirconium compound has a chemical formula shown in formula 1, wherein R1, R2, R3 and R4 are each independently selected from one of H, methyl, ethyl or propyl. In the present application, nucleophilic substitution occurs between a pyrrole alkali metal salt and zirconium tetrachloride, and then the zirconium compound containing a cyclopentadiene and a pyrrole group is formed by reacting with cyclopentadiene. Compared with (cyclopentadienyl)tris(dimethylamino)zirconium, the zirconium compound has excellent thermal stability and excellent reactivity and volatility, which is helpful to form a high-purity low-impurity and uniform thin film, and greatly improves the quality of the thin film.

The application discloses a preparation method of DL-tartaric acid, which uses maleic anhydride as raw material, uses WO3-SiO2-ZrO2 solid acid as a catalyst, and is prepared through catalytic oxidation reaction under the condition of an oxidant. The catalyst is prepared through the following steps: mixing and dissolving a tungsten-containing compound and a zirconium-containing compound; adding silica sol, a surfactant and a precipitant to form a gel, and then performing filtration, washing and calcination to obtain the catalyst. Since the active species and the carrier in the catalyst have strong interaction, the recycling rate of the catalyst is high, so that the residual amount of heavy metal tungsten in the prepared tartaric acid crystal is effectively reduced, the DL-tartaric acid yield is still high during recycling, the production cost of the tartaric acid is reduced, and the catalyst is suitable for large-scale production.

A method of forming a solid-state electrolyte powder includes the following steps. A zirconium compound layer is formed on an inner surface of a container. A precursor mixture is placed on the zirconium compound layer. The precursor mixture includes a first salt group and a second salt group. The first salt group includes zirconium source compound, lanthanum source compound, aluminum source compound, titanium source compound, tantalum source compound, or combinations thereof. The second salt group includes lithium source compound. An aerobic sintering process is performed to form the solid-state electrolyte powder.

The application belongs to the technical field of inorganic materials, and particularly relates to a preparation method of sodium zirconium cyclosilicate ZS-9 and application thereof. The preparation method comprises the following steps: reacting a silicon salt, an alkali and a zirconium-containing compound, adjusting pH, and filtering, so as to obtain the sodium zirconium cyclosilicate ZS-9, wherein the molar ratio of the silicon salt, the alkali and the zirconium-containing compound is 3.8-4.2:4-4.5:1. The preparation method of the sodium zirconium cyclosilicate ZS-9 is relatively mild in reaction condition, does not need special high-pressure reaction equipment, and is easy to realize industrialization. Compared with the prior art, the obtained sodium zirconium cyclosilicate ZS-9 has higher purity, yield and potassium ion exchange capacity.

The invention relates to a glaze material with stable color after coloring and sintering for the surface of sanitary ceramics, and belongs to the technical field of ceramics, the glaze material comprises a zirconium compound, vanadium zirconium blue, a metal oxide, wollastonite, carboxymethyl cellulose, sodium tripolyphosphate and deionized water; the zirconium compound comprises neodymium zirconate, zirconium phosphate and zirconium silicate; the metal oxide comprises zinc oxide. Neodymium zirconate selected in the invention can absorb light with a specific wavelength, is adjustable in color and is not easy to decompose at a high temperature; the vanadium zirconium blue is excellent in high-temperature stability and good in compatibility with zirconium silicate; zirconium phosphate can chelate transition metal ions, namely vanadium ions, in vanadium zirconium blue, and charge transfer and color generation are stabilized. Zirconium silicate can wrap coloring ions in a system and reduce migration of the coloring ions in the glaze; therefore, the four components are combined, so that the glaze has color stability effectively. In addition, zirconium silicate, zinc oxide and wollastonite can synergistically improve the smoothness of the glaze from different aspects, and the appearance attractiveness of sanitary ceramics using the glaze is improved.

The application belongs to the field of silver catalysts, and relates to a composite alpha-alumina carrier for a silver catalyst for ethylene oxidation to produce ethylene oxide, a preparation method of the composite alpha-alumina carrier, the silver catalyst and application. The composite alpha-alumina carrier comprises an alpha-alumina carrier and a porous alumina film containing zirconium coated outside the alpha-alumina carrier. The preparation method of the composite alpha-alumina carrier comprises the following steps: (1) dissolving an aluminum-containing compound, a pore-forming agent and a zirconium-containing compound in water, and preparing a solution after stirring; the pore-forming agent is urea, hexanediamine, sucrose or starch; (2) immersing the alpha-Al2O3 carrier in the solution obtained in step (1), and performing drying and calcination after leaching, to obtain the composite alpha-alumina carrier coated with a porous alumina film containing zirconium on the outer surface. The silver catalyst prepared from the alpha-alumina carrier of the application shows good reactivity and selectivity in the process of ethylene oxidation to produce ethylene oxide.

A method for manufacturing an oxide-base solid electrolyte of a lithium battery includes the steps of: placing a zirconium-contained compound and a lanthanum-contained compound into a first ball mill for grinding and then performing an oil bath assisted vacuum concentration and a first stage sintering operation to obtain a zirconium lanthanum compound; placing the zirconium lanthanum compound, a lithium-contained compound, a gallium-contained compound, an aluminum-contained compound and a further lanthanum-contained compound into a second ball mill for grinding and then performing another oil bath assisted vacuum concentration and a second stage sintering operation to obtain a plurality of modified LLZO agglomerates; and placing the modified LLZO agglomerates into a jet mill and a wet grinding mill for grinding and then performing a water bath assisted vacuum concentration to obtain a plurality of modified LLZO powders.

A process for producing an oxide-based solid electrolyte for a lithium battery, comprising the following steps: introducing a zirconium-containing compound and a lanthanum-containing compound into a first ball mill for grinding, followed by oil bath-assisted vacuum concentration and a first sintering process to obtain a zirconium-lanthanum compound; introducing the zirconium-lanthanum compound, a lithium-containing compound, a gallium-containing compound, an aluminum-containing compound, and another lanthanum-containing compound into a second ball mill for grinding, followed by further oil bath-assisted vacuum concentration and a second stage of a sintering process to obtain a variety of modified LLZO agglomerates;and the introduction of the modified LLZO agglomerates into a jet mill and a wet mill for grinding and subsequent water bath-assisted vacuum concentration to obtain a variety of modified LLZO powders.

The application discloses a synthesis method of high softening point silicon oxide, and belongs to the technical field of silica preparation process. The method adds a small amount of titanium compound and / or zirconium compound in the process of synthesizing quartz sand, and the density and softening point of the synthesized quartz sand are significantly improved. In particular, the quartz sand with the titanium compound and the zirconium compound added simultaneously has more excellent softening point and density.

A hydrosilylation curable textile coating composition comprises: (a) a linear organopolysiloxane polymer having at least two alkenyl and / or alkynyl groups per molecule; (b) a reinforcing filler comprising at least one of fumed silica, precipitated silica, or calcium carbonate; (c) a linear trimethyl terminated polydimethyl methylhydrogen siloxane containing at least two silicon-bonded hydrogen groups per molecule; (d) a hydrosilylation cure catalyst; (e) an organosilicon resin; and (f) an adhesion promoter comprising a mixture and / or reaction product of: (i) one or more alkoxysilanes having an epoxy group in the molecule; (ii) a linear organopolysiloxane oligomer containing at least one alkenyl group and at least one hydroxy or alkoxy group per molecule; and (iii) an organometallic condensation reaction catalyst comprising organoaluminum or organozirconium compounds. Air bags and air bag fabrics can be coated with the hydrosilylation curable textile coating composition, and the resulting air bags and fabrics generally have enhanced scrub resistance.

A method for preventing or reducing knock in a hydrogen fueled combustion engine is described. The method involves lubricating the crankcase of the engine with a lubricating oil composition that includes about 50 to about 3000 ppm of zirconium from one or more zirconium compound, based on total weight of the lubricating oil composition.

To provide a method of manufacturing a solid electrolyte oxide for a lithium battery.SOLUTION: Polishing is performed by injecting a zirconium compound and a lanthanum compound into a first ball mill having ultrapure water and methanol and oil bath decompression condensation is then performed. Next, a first stage sintering operation is performed to generate a nitrogen argon atmosphere sintering reaction to generate a zirconium lanthanum compound. Then, polishing is performed by injecting a lithium compound, a gallium compound, an aluminum compound, another lanthanum compound, and the zirconium lanthanum compound into a second ball mill containing ultrapure water, and oil bath decompression condensation is then performed. Next, a second stage sintering operation is performed to generate an aerobic sintering reaction to generate a plurality of modified LLZO blocks. Polishing is performed by injecting the plurality of modified LLZO blocks into a jet mill and a wet polisher, and water bath decompression condensation is then performed, to obtain modified LLZO powder, that is, a solid electrolyte oxide for a lithium battery.SELECTED DRAWING: Figure 1

The invention discloses a method for preparing sequence-controlled degradable copolyester based on a zirconium complex catalyst. The method comprises the following steps: S1, synthesizing a tert-butyl amino triphenol ligand; s2, a zirconium compound, a tert-butyl amino triphenol ligand and a lactate compound are subjected to a reaction, and a zirconium complex catalyst is obtained; s3, under the catalysis of a zirconium complex catalyst, at least one cyclic ester monomer is subjected to a ring-opening polymerization reaction, and thus the degradable copolyester with the controllable sequence and steric regularity is obtained. The dicyclohexyl glycolide monomer structure and the methyl cyclohexyl glycolide monomer structure contain a rigid group cyclohexyl, so that the glass transition temperature of the polyester can be well improved, and the application range of the polyester can be widened. The glass transition temperature of one of the copolyesters prepared by the invention is as high as 86.8 DEG C. Meanwhile, the invention provides a method which is simple in process and easy to operate and is used for preparing copolyester, and the method has the advantages of controllable process, mild reaction conditions, narrow molecular weight distribution, controllable sequence and the like.

The present invention pertains to a liquid addition-curable silicone rubber composition for airbags, the composition comprising: (A) a linear organopolysiloxane having a polymerization degree of 50-2,000 and including an alkenyl group bonded to two or more silicon atoms in one molecule; (B) a powdery three-dimensional network organopolysiloxane resin; (C) a linear organohydrogenpolysiloxane in which terminals are blocked with a trialkylsilyl group and which includes two or more hydrosilyl groups in one molecule; (D) a silica fine powder; (E) a surface treatment agent selected from silazanes or chlorosilanes; (F) a hydrosilylation reaction catalyst; (G) an organic silicon compound including an adhesiveness-imparting functional group; and (H) a titanium or zirconium compound including one or more ligands represented by formula (1). As a result, provided are: a liquid addition-curable silicone rubber composition for airbags, the composition having excellent sliding detachment resistance and storage stability; and an airbag having a cured coating made of said composition.

Providing a metal surface treatment agent capable of high-temperature firing and capable of imparting high corrosion resistance to a metal substrate. A metal surface treatment agent comprising a silicate compound (A); an alkali metal salt (B) other than a silicate compound, other than a vanadium compound, and other than a zirconium compound; a vanadium compound (C); a zirconium compound (D); and water, wherein the silicon element content is 10 mass% or more with respect to the total solid content of the metal surface treatment agent. Preferably, the silicate compound (A) is an alkali metal silicate.

Provided is an additive composition for an electrode of a lithium ion secondary battery, the additive composition containing lithium phosphate and a zirconium compound, and the zirconium element content with respect to the total amount of the lithium phosphate and the zirconium compound being 100-10,000 mass ppm.

The application relates to the technical field of antibacterial agents, and provides a preparation and application of superfine cubic sodium zirconium phosphate and a loaded antibacterial agent, which solve the defect of large particle size of zirconium phosphate obtained by an existing preparation method and comprises the following preparation steps: (1) a zirconium-containing compound and a phosphate-containing compound are weighed, a crystal form inducer is added, and then a mixed and uniform composite powder is formed by grinding for more than 30 min; (2) a sodium nitrate and ammonium oxalate-containing aqueous solution is prepared; (3) the prepared composite powder in the first step is weighed according to a proportion, the composite powder is slowly added into the aqueous solution prepared in the step (2) under continuous stirring, and after all the composite powder is added, continuous stirring is carried out and the solution is kept boiling for 2-3 hours; (4) after the reaction is completed, the solution is cooled to room temperature, the pH value is adjusted to weak acidity, and a cationic organic flocculating agent is added, so that cubic sodium zirconium phosphate precipitates are obtained; after dehydration, cleaning and drying, cubic sodium zirconium phosphate powder is obtained.

Provided is a metal surface treatment agent that enables high-temperature sintering and imparts high corrosion resistance to a metal base material. A metal surface treatment agent contains a silicic acid compound (A), an alkali metal salt other than the silicic acid compound, a vanadium compound, and a zirconium compound, and the content of silicon is 10% by mass or more relative to the total solid content of the metal surface treatment agent. The silicic acid compound (A) is preferably an alkali metal silicate.

The invention belongs to the technical field of polymer synthesis, and particularly relates to an aromatic acid zirconium-zirconium phosphate / polyarylene sulfide hydrophilic compound and a preparation method thereof. The invention provides a preparation method of an aromatic acid zirconium-zirconium phosphate / polyarylene sulfide hydrophilic compound, which comprises the following steps: preparing an aromatic acid zirconium compound from a polyfunctional group active aromatic acid compound and a soluble zirconium salt through a chemical synthesis method, and synthesizing zirconium phosphate; then, active polyarylene sulfide is prepared from the sulfide and a polymeric monomer through a polymerization reaction; finally, the aromatic acid zirconium compound, zirconium phosphate and active polyarylene sulfide are subjected to in-situ compounding or blending extrusion, and the aromatic acid zirconium-zirconium phosphate / polyarylene sulfide hydrophilic compound is obtained. A polar hydrophilic group is added to a side chain of a polyphenylene sulfide molecule and fused with a high-polarity hydrophilic zirconium compound with multiple molecular structures, so that the high-polarity hydrophilic polyarylene sulfide material with high strength and high stability is formed.

The invention belongs to the technical field of vulcanized rubber degradation, and particularly relates to a zirconium-aluminum bimetallic catalyst system and a method for chemically degrading polydiene vulcanized rubber. The zirconium-aluminum bimetallic catalyst system provided by the invention comprises a zirconium compound and an aluminum compound, the zirconium compound contains a mono-cyclopentadienyl ligand or a di-cyclopentadienyl ligand; the aluminum compound contains aluminum hydrogen bonds and / or aluminum alkyl bonds; the molar ratio of the zirconium compound to the aluminum compound is 1: (1-50). When the zirconium-aluminum bimetallic catalyst system provided by the invention is used for chemically degrading the polydiene vulcanized rubber, the compatibility of the catalyst in the system is good, the liquid polydiene rubber obtained by degradation contains a sulfydryl functional group, the number-average molecular weight is (1-46) * 103 g / mol, and the efficient degradation of the polydiene vulcanized rubber can be realized.

This application provides a solar cell and its fabrication method, a tandem solar cell, and a photovoltaic module. The fabrication method of the solar cell includes the following steps: providing a semiconductor substrate having a first surface and a second surface disposed opposite to each other; coating the first surface and / or the second surface of the semiconductor substrate with a conductive paste and sintering to form electrodes; wherein, by mass percentage, the conductive paste comprises: 65%~80% conductive powder, 1%~8% glass powder, 5%~10% organic carrier, and the balance being additives; the glass powder contains lead; the additives include zirconium-containing compounds and gallium-containing compounds. The solar cell prepared by this application can effectively improve the acetic acid resistance and photoelectric conversion efficiency of the solar cell, and improve the long-term reliability of the solar cell.

The invention relates to the field of catalysts, in particular to an iron-nitrogen-carbon-based catalyst and a preparation method and application thereof. The preparation method comprises the following steps: dissolving diethyl imidazole and zinc nitrate hexahydrate in an organic solvent according to a specific mass ratio to obtain a first mixed solution; dissolving an iron-containing compound, a sulfur-containing compound and a zirconium-containing compound in an organic solvent according to a specific molar mass ratio to obtain a second mixed solution; mixing and stirring the first mixed solution and the second mixed solution until the mixture is adhesive, and heating until the mixture is powdery; and heating the powdery mixture from room temperature to 900-1000 DEG C in an inert atmosphere at a heating rate of 2.5-7.5 DEG C / min, carrying out heat preservation for 1-5 hours, and cooling to room temperature at a cooling rate of 2.5-7.5 DEG C / min after calcination is completed, so as to obtain the catalyst. The preparation method is simple and convenient to operate, short in synthesis time, high in yield and beneficial to promotion of development of a sustainable energy conversion technology.

The invention relates to the technical field of rhenium-based catalysts, in particular to a rhenium-based catalyst and a preparation method and application thereof.The catalyst comprises an active component and an auxiliary component which are loaded on a carrier; the active component comprises a rhenium-containing compound, and the auxiliary component comprises a zirconium-containing compound and / or a boron-containing compound; the carrier is aluminum oxide, and the auxiliary agent component is combined with an alkaline hydroxyl group on the surface of the carrier to reduce the content of the alkaline hydroxyl group, so that the active component is accurately loaded on an acidic hydroxyl group on the surface of the carrier to form an active site; lewis acid sites are additionally introduced into the auxiliary component, and the auxiliary component is also used for loading the active component and increasing the active sites; the additive component and the active component have a synergistic effect and are used for catalyzing a double decomposition reaction of unsaturated fatty acid ester and olefin, so that the technical effects that the conversion rate of the unsaturated fatty acid ester is 43-65%, and the selectivity of the product is 56-68% are achieved.

is disclosed. The method includes the following steps: (A) Dissolving a zirconium compound in an inorganic acid and adding a rare earth oxide to form a first mixture solution; (B) Creating a yttrium solution in an organic solvent or deionized water, then adding it to the first mixture solution with a dispersant and chelating agent, and performing ultrasonic vibration to form a second mixture solution; (C) Heating and stirring the second mixture solution to form a sol-gel mixture; (D) Performing thermal decomposition on the sol-gel mixture to create a zirconia precursor; (E) Performing heat treatment on the zirconia precursor to obtain the final zirconia powder.