The preparation method comprises the following steps: (1) preparation of bio-based
polyol: mixing peanut shell
powder with a liquefying
reagent, starting condensate water and a stirrer, heating a constant-temperature
oil bath pan to 135-145 DEG C, slowly dropwise adding a catalyst, starting timing after the catalyst is completely added, and stopping the reaction; after reacting for 2-3 hours, quickly cooling to
room temperature to obtain bio-based
polyol; and (2) preparation of the bio-based
polymer: mixing the bio-based
polyol, the sieved peanut shell
powder, deionized water and a catalyst I to obtain the bio-based
polymer. According to the preparation method and application of the bio-based
polymer capable of recovering the
high strain, the preparation method is reasonable, the peanut shells are used as the
raw material to prepare bio-based polyol, energy consumed in the production process is low, carbon emission is reduced, and the prepared bio-based polymer is high in strain, low in modulus and high in
recovery rate. The shape fixing rate, the shape
recovery rate and the
cycling stability are good, and the application prospect is wide.