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51results about How to "High curing activity" patented technology

Active ester curing agent and epoxy resin composition

The invention provides an active ester curing agent and relates to the field of copper-cladding plates. The active ester curing agent has a dicyclopentadiene-phenyl ester alternate structure. On one hand, a dicyclopentadiene structure of the active ester curing agent is capable of well preserving excellent properties such as low hygroscopicity, dielectric constant and dielectric loss angle tangentcaused after the reaction between the curing agent and epoxy resin. On the other hand, the content of an active ester structure in the structure is relatively high, so that the curing agent has veryhigh reaction activity in the reaction with the epoxy resin. The preparation method of the active ester curing agent is easy in operation, the raw materials are easily available, and the large-scale industrial production can be realized. The invention further provides an epoxy resin composition. By virtue of reasonable matching of the active ester curing agent, the epoxy resin and an imidazole compound in a specific proportion, the epoxy resin composition is high in curing activity and has a good curing effect, and a cured condensate has excellent dielectricity and water absorption property and can be used for preparing prepregs, laminated boards and copper-cladding plates.
Owner:SHAANXI SHENGYI TECH

Vegetable oil-based epoxy prepolymer and preparation method thereof, vegetable oil-based UV curing prepolymer as well as preparation method and application thereof

The invention discloses a vegetable oil-based epoxy prepolymer and a preparation method thereof. The vegetable oil-based epoxy prepolymer has a structure shown by a general formula (I) shown in the specification. The invention further discloses a vegetable oil-based UV curing prepolymer as well as a preparation method and application thereof. According to the method, the vegetable oil-based epoxyprepolymer is firstly prepared by prepolymerizing a vegetable oil D-A reaction product with water and epichlorohydrin, and then the vegetable oil-based epoxy prepolymer reacts with pentaerythritol triacrylate to obtain the vegetable oil-based UV curing prepolymer; vegetable oil is introduced into the UV curing prepolymer, thereby greatly reducing the use amount of conventional petrochemical-derived raw materials. The vegetable oil-based UV curing prepolymer provided by the invention has very high UV curing activity and can be rapidly cured into a film in 10 to 60 s, and the cured film is goodin adhesion and excellent in physical properties, mechanical properties and thermal properties, and can be widely applied to the fields of UV curing coatings, inks, adhesives, 3D printing and other UVcuring materials.
Owner:SOUTH CHINA AGRI UNIV +1

Self-emulsifying waterborne epoxy resin curing agent and preparation method thereof

The invention discloses a self-emulsifying waterborne epoxy resin curing agent, which is prepared from 1 to 10 parts of amino silicon oil, 20 to 30 parts of epoxy resin, 0.01 to 5 parts of a reactionauxiliary agent, 120 to 250 parts of a solventand 1 to 10 parts of an end-capping agent. The preparation method comprises the following steps: firstly, dissolving amino silicone oil in thesolvent, then adding the reaction aid, uniformly stirring, dropwise adding a mixed solution of epoxy resin and the solvent at a constant speed under the condition of 60-80 DEG C and in an inert gas atmosphere, and continuously reacting after dropwise adding is finished; continuously dropwise adding a mixed solution of the end-capping reagent and the solvent at a constant speed, and carrying out an end-cappingreaction; and finally adding a regulator, and carrying out reduced pressure distillation. The self-emulsifying waterborne epoxy resin curing agent disclosed by the invention has self-emulsifying anddefoaming properties, and can have excellent curing properties for different waterborne epoxy resins, so that a cured epoxy resin film has good properties such as heat resistance, weather resistance,electric insulativity, chemical resistance and hydrophobicity.
Owner:陕西立高涂料有限公司

Long-acting weather-resistant, chlorine-salt corrosion-resistant polyester powder coating and preparation method thereof

The invention belongs to the technical field of polyester powder coating preparation, and in particular relates to a long-acting weather-resistant, chlorine-salt corrosion-resistant polyester powder coating and a preparation method. The main raw materials of the powder coating of the present invention are: 530-560 parts of polyester resin, 45-60 parts of TGIC, 10-15 parts of trimesic acid triglycidyl ester, 120-180 parts of titanium dioxide, and 80-120 parts of barium sulfate , 8‑12 parts of brightening agent, 7‑10 parts of leveling agent. The polyester resin used in the powder coating of the present invention has a good linear structure, which ensures excellent fluidity; the powder coating uses a larger amount of trifunctional curing agent TGIC, and is matched with triglycidyl trimesic acid with a low melting point and excellent water resistance Esters are used as low-temperature curing agents to further improve the crosslinking density and water resistance of the coating film, and finally ensure long-term weather resistance and chloride salt corrosion resistance. The final powder coating product can be used for low-temperature curing at 160°C. The coating film prepared by it has good long-term weather resistance and chlorine salt corrosion resistance, and is especially suitable for infrastructure spraying on highways such as guardrails and bridges.
Owner:安徽鑫友高分子新材料科技有限公司

Anti-thick coating pinhole, excellent acid and alkali resistance powder coating and preparation method thereof

ActiveCN112011260BGood acid and alkali resistanceOvercome the shortcomings of poor acid and alkali resistanceAnti-corrosive paintsPolyether coatingsPolymer scienceLow temperature curing
The invention belongs to the technical field of powder coatings, and in particular relates to a powder coating with excellent pinhole resistance and acid and alkali resistance and a preparation method thereof. The parts by weight of the main raw materials of the powder coating of the present invention are: 530-550 parts of hydroxyl polyether resin, 40-50 parts of B1530 curing agent, 150-200 parts of talcum powder, 120-150 parts of barium sulfate, 8-12 parts of brightening agent Parts, 7-10 parts of leveling agent; Hydroxy polyether resin is prepared by polycondensation of materials with the following molar fractions: the molar fractions of each component are: 1,4-cyclohexanedimethanol 4-8 , 1,6-hexanediol 3-6, resorcinol diglycidyl ether 5-10, propylene oxide 30-45, triglycidyl isocyanurate 4-8, octyl glycidyl ether 6-13 . The present invention uses high-functionality hydroxyl polyether resin as the raw material, the hydroxyl value is 15-20mgKOH / g, the amount of B1530 curing agent required for curing is small, the cost of powder coating is low, and it can be cured at 175°C / 15min at low temperature, and The prepared coating film has good resistance to pinholes in thick coating, and the high-functionality polyether has excellent acid and alkali resistance, and can be used for coating metal facilities in industrial cleaning places.
Owner:安徽鑫友高分子新材料科技有限公司
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