The invention discloses a block solid defoamer and its preparation method. The components and parts by weight include: 10-90 parts of fatty acid salt, 1-20 parts of active ingredient, 0-10 parts of emulsifier, and 10 parts of structuring agent. ~90 parts, appropriate amount of acid-base regulator. The preparation is to first neutralize the fatty acid mixed in proportion with sodium hydroxide solution to form fatty acid salt, then emulsify the active ingredient with an emulsifier, compound the active ingredient with fatty acid salt and structuring agent, mix well, and properly Add an acid-base regulator, and after cooling, discharge the material into plastic bags, and further cool and shape it to obtain a solid block product. The invention has the advantages of simple production process, convenient operation, high safety, non-toxicity, non-corrosion, good environmental compatibility and no environmental pollution. The product has low surface tension, fast dispersion in water, fast defoaming, long antifoaming time, less dosage, wide source of raw materials, high cost performance, not only used in papermaking and sewage treatment industries, but also in petroleum, mineral processing, chemical and other industries.