The invention discloses a wet method
etching process for
crystal silicon wafers, which mainly comprises a back side
polishing process. After
etching and edge removing, the
polishing process performed to the back sides of the
crystal silicon wafers through a
polishing solution is added, the temperature of the polishing solution in polishing is 5-30 DEG C, the polishing time is 10 seconds to 10 minutes, and the polishing solution contains, by
mass, 0.5%-10% of HF, 35%-55% of HNO, 45%-55% of H2SO4 and 5%-30% of
acetic acid. By adding the back side polishing process, the back sides of the
silicon wafers can be smooth, back reflection of the silicon wafers is strengthened, and absorption of long-
wave band spectrums in
sunlight is enhanced, thereby improving
light energy conversion and short-circuit current (Isc) of a battery and finally improving the conversion efficiency of the battery. In addition, the back of the smooth battery further facilitates combination of follow-up aluminum-
silicon alloy and a silicon body, improves
ohmic contact, strengthens the
light reflection effect of an interface, improves variable output circuit (Voc), and finally improves the conversion efficiency of the battery.