This invention discloses a perovskitesolar cell and its fabrication method. The method includes: spin-coating a mixed solution of lead iodide and HIAM-4024 or HIAM-4025 onto the surface of an electrontransport layer, followed by annealing to obtain a lead iodide layer; and spin-coating an organic halide solution onto the surface of the lead iodide layer, followed by annealing to obtain a perovskite layer. This invention introduces HIAM-4024 or HIAM-4025 into the lead iodide layer, allowing high-energy photons to be filtered through HIAM-4024 or HIAM-4025. Through down-conversion, it emits photons in the visible light range, which are further utilized by the underlying perovskite absorber, thereby improving the light energy utilization of the perovskite solar cell. Furthermore, both HIAM-4024 and HIAM-4025 can effectively filter ultravioletradiation that could damage the device, further enhancing the light energy utilization of the perovskite device.