The invention discloses a high-multiplying power lithium ion battery and a preparation method thereof. The lithium ion battery comprises a cathode plate, an anode plate, a composite diaphragm and an electrolyte solution, and the surfaces of the diaphragm are coated with composite conductive layers; each composite conductive layer is composed of a bonding agent, a conductive agent and micropores; the cathode plate and the anode plate are each of a full-tab structure. The preparation method comprises the steps that the diaphragm coated with the composite conductive layers, the cathode plate and the anode plate are subjected to a winding process to prepare a wound core, and the wound core is subjected to the processes of packaging, baking, liquid injecting, hot-cold pressing, forming and capacity grading to prepare the high-multiplying power lithium ion battery. According to the high-multiplying power lithium ion battery and the preparation method thereof, by improving the characteristics of the interfaces between the diaphragm and cathode and anode membranes and optimizing the structural design of the battery, the bonding performance of the contact interfaces between the diaphragm and the cathode and anode plates is improved, the lithium ion transfer resistance between the different interfaces is decreased, the electronic conductivity of the cathode and anode plates is enhanced, the porosity and the air permeability of the composite diaphragm are improved, wetting of the electrolyte solution to the diaphragm is improved, the retaining capacity of the electrolyte solution in the battery is improved, the high-multiplying power performance of the lithium ion battery is greatly improved, the high-multiplying power discharge capacity retention rate is increased by 10% or above compared with the prior art, and the high-multiplying power lithium ion battery is suitable for industrialized production.