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166 results about "Ion permeation" patented technology

Preparation method of metal-organic framework material/polymer composite proton exchange membrane

The invention relates to a preparation method of a metal-organic framework material / polymer composite proton exchange membrane. The method is characterized by comprising the following steps: dissolving a polymer matrix and a certain amount of metal-organic framework material with an organic solvent and carrying out ultrasonic dispersion to form a uniform membrane liquid; coating the flat and smooth surface of a glass plate with the obtained membrane liquid, and then removing the organic solvent to obtain a composite membrane; and carrying out vacuum drying on the composite membrane for 24 hours to prepare the composite proton exchange membrane for an all-vanadium redox flow battery. The composite proton exchange membrane is smooth in surface; the internal structure of the membrane is regular; the membrane is uniform in thickness and free of a defect; and the thickness is 10-300 microns. The composite proton exchange membrane provided by the invention has excellent vanadium ion permeation blocking ability, keeps excellent proton transfer performance, overcomes the defect of relatively high vanadium ion permeability of an existing all-vanadium redox flow battery membrane, and has the advantages of being simple in preparation process, high in proton transmittance, excellent in vanadium blocking property, excellent in oxidative resistance, easy to industrially amplify and the like.
Owner:INST OF CHEM CHINESE ACAD OF SCI

Electrolyte membrane and application of composite membrane thereof in liquid-flow energy storage battery with acidic electrolyte

The invention relates to an electrolyte membrane and application of a composite membrane thereof in a liquid-flow energy storage battery with acidic electrolyte. The electrolyte membrane uses polybenzimidazole or other aromatic heterocyclic polymers as a base membrane or is doped with a strong-acidity solution through composite techniques comprising an organic / inorganic technique, an organic / organic technique, a blending technique, a crosslinking technique, a strengthening technique and the like so that the acid content, the proton conductivity and the mechanical strength of the composite membrane are improved. Different from the traditional electrolyte membrane containing functional groups, the novel electrolyte membrane does not contain iron conduction groups, but utilizes acid in the electrolyte as the electrolyte to conduct protons. Due to the adoption of a Hopping conduction mechanism, the membrane reduces the iron permeation and the water migration of the liquid-flow energy storage battery, greatly reduces the crossing of anode and cathode electrolyte and prolongs the service life of the electrolyte. The preparation process is simple, and the prepared electrolyte membrane can effectively satisfy the requirements on the performance and the stability of the liquid-flow energy storage battery.
Owner:DALIAN RONGKE POWER

Polymer modified rubber mortar used for building leveling layer and construction method of polymer modified rubber mortar

ActiveCN103342520AGood flexibilitySignificant flexibility advantageCovering/liningsSolid waste managementFiberPolymer modified
The invention discloses polymer modified rubber mortar for a building leveling layer. The polymer modified rubber mortar is formed by doping three modified materials including rubber powder, a polymer and an organic fibre into modified cement mortar. The polymer modified rubber mortar is formed by mixing the following components in parts by weight: 30-40 parts of cement, 5-20 parts of water, 2-10 parts of the polymer, 50-90 parts of sand, 5-15 parts of the rubber powder, 0.05-0.15 part of the organic fibre, 0-5 parts of mineral admixtures, 0-1 part of an auxiliary, and 0-0.5 part of an additive. According to the freshly-mixed polymer modified rubber mortar, the thickness is controlled to be 7cm, during the curing period of 7 days, the compressive strength of the mortar is not less than 10 MPa, the rupture strength is not less than 3.5 MPa, during the curing period of 28 days, the compressive strength of the mortar is not less than 15 MPa, the rupture strength is not less than 5 MPa, the chloride ion permeation coefficient is not larger than 50*10<-14>m<2>/s, and the heat conductivity coefficient is not larger than 0.5W/m.k. The polymer modified rubber mortar disclosed by the invention can be used for effectively solving the problems of sugaring, peeling, crispiness, bulging, cracking and the like existing in the traditional cement mortar leveling layer, has the performance advantages of permeability resistance, crack prevention, thermal insulation, high tenacity and the like, can fully utilize waste rubber, can turn waste into wealth, and is suitable for various building leveling layers.
Owner:CHINA UNIV OF GEOSCIENCES (WUHAN)

Self-electroosmosis hydrogel adhesive film

InactiveCN101862505APromote osmotic absorptionSelf-produced electroosmotic effectElectrotherapyOrganic filmAdhesive
The invention relates to a self-electroosmosis hydrogel adhesive film, which combines an electrochemical primary batter consisting of two polar materials with different electrochemical potential difference with functional active substance-containing hydrogel. A method for manufacturing the self-electroosmosis hydrogel adhesive film comprises the following steps of: printing conductive paste on an organic film to form a collector layer; producing a positive electrode layer and a negative electrode layer and printing the positive electrode layer and the negative electrode layer on the collector layer respectively; adhering all the layers on a non-woven fabric substrate; coating a conductive adhesive layer on the two electrodes respectively; and coating a functional active substance-containing hydrogel layer on the conductive adhesive layer. During use, the hydrogel adhesive film is contacted with the skin of a human body, and the two electrodes and the skin of the human body form a current loop through the hydrogel comprising a certain amount of moisture, so that permeation rate of the active substance can be increased and the adsorption rate of the skin on the active substance can be increased. The hydrogel adhesive film has the advantages of overcoming the defects that a power supply needs to be added, the film cannot be used at any time and the cost is high in the conventional ion permeation technique, and effectively increasing the permeation rate of the functional active substance, along with simple structure, low cost, convenient storage and carrying and convenient use.
Owner:SICHUAN UNIV +1

Preparation method for selecting SPEEK/GO/TiO2 composite ion selection membrane in nanometer insertion layer

The invention relates to the field of a diaphragm for an all-vanadium oxygen-reduction redox flow battery, in particular to a preparation method for selecting a sulfonated polyetheretherketone / graphene oxide / titanium dioxide nanometer particle composite ion selection membrane in a nanometer insertion layer. By the preparation method, the problems of vanadium ion permeation seriousness, poor ion selectivity and high cost of a proton exchange membrane in an existing commercial diaphragm are solved. The low-cost sulfonated polyetheretherketone (SPEEK) is used as a base film, a graphene oxide / titanium dioxide nanometer particle (GO / TiO2) insertion layer composite material is used for controlling an ion selection conduction passage, and the SPEEK / GO / TiO2 composite ion selection membrane is prepared by a film formation method such as dispersion step by step and solution pouring. The composite ion selection membrane prepared by the invention has the advantages of favorable ion selection conductivity, excellent vanadium ion blocking performance, favorable mechanical property, chemical stability and excellent single VRB battery performance and the like and is widely applied to the field ofthe all-vanadium oxygen-reduction redox flow battery.
Owner:山东奥德储能科技有限公司

Method for measuring chloride ion penetration resistance of concrete

The invention belongs to the technical field of performance testing method of civil engineering materials, and relates to a method for measuring chloride ion penetration resistance of concrete. An apparatus for measuring chloride ion penetration resistance of concrete is used for realization, and a concrete technological process comprises the following five steps: a concrete test piece is prepared, the concrete test piece is pretreated, the concrete test piece is clamped and mounted, the concrete test piece resistor is measured, and permeability of the concrete test piece is calculated and analyzed. Low voltage high-frequency AC electricity whose voltage is 1 volt and frequency is 1000 Hertz is used for measuring resistor of the concrete test piece which is pretreated by saturated water, resistance value reflects capability of chloride ion penetration resistance of the concrete test piece, so that the phenomenons that a polarization reaction is easy to happen in a DC test method and heat is generated in a solution under the effects of voltage for a long time are overcome, the disadvantage of generation of interference on resistance value is overcome, and ASTM C1202 which is recommended by American Society for Testing and Materials is improved; the method has the advantages of scientific and reliable principles, simple measuring flow, fast measuring speed, accurate measuring results, and easy promotion and usage.
Owner:QINGDAO TECHNOLOGICAL UNIVERSITY

Marine electric field measuring device

The invention relates to a marine electric field measuring device which comprises a sealing body, a signal acquisition processing system in the sealing body, a plurality of pairs of electric field sensors, a signal amplification system, and a signal transmission system communicated with the signal acquisition processing system in the middle of the sealing body, wherein one end of each electric field sensor is fixedly connected with a housing of the sealing body in a sealing manner; the other end of each electric field sensor is communicated with a data acquisition system via the signal amplification system; cavities of the electric field sensors internally comprise electrolytes and electric field measuring electrodes immersed in the electrolytes; one end of each cavity is a sealing end; the other end of each cavity is an ion permeation end; and one end of each electric field measuring electrode is connected with a cable in a sealing manner. The measuring device has the main advantages that the measuring device is simple in structure, stable in electrode potential, short in equilibrium time and high in measuring accuracy; an influence of marine turbulence on the electric field measuring electrodes is small; the measuring device has an effect of preventing a marine organism from fouling; the sensors are convenient to calibrate and check; electrochemical activation can be performed; the service lives of the electrodes are long; and the measuring device is suitable for measuring marine, potamic and telluric weak electromagnetic fields.
Owner:SUZHOU GREENTEK
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