91 results about "Mercury contamination" patented technology

An in situ soil remediation system may be used to remove or reduce levels of mercury contamination within soil. The soil remediation system may also remove or reduce levels of other contaminants within the soil. Mercury may be vaporized within the soil by a heating system. The vaporized mercury may be removed from the soil by a vacuum system. The vaporized mercury may pass through heated risers that elevate the vaporized mercury. After the vaporized mercury passes from the heated risers, the vaporized mercury may be allowed to cool, condense, and flow downward to a treatment facility. Removing mercury from the soil as a vapor may provide an economical, safe, and efficient way to remediate mercury contaminated soil.

The invention relates to the field of sewage treatment, in particular to a treatment method of mercury-polluted water. The mercury-polluted water treatment process mainly comprises pretreatment and mercury removal, wherein the pretreatment is as follows: pretreatment is carried out on the collected polluted water, the suspended matter concentration in the water body is less than or equal to 100mg/L; mercury removal is as follows: (1) inorganic mercury is removed; (2) mercury and mercuric salt are removed by adsorption; secondary adsorption is carried out by an obligate zeolite and hydroxide radical activated carbon, wherein the hydroxide radical activated carbon further adsorbs inorganic mercuric salts in the polluted water; (3) mercury and mercuric salts are removed by ion exchange, and final treatment is carried out on mercury in the polluted water, so as to enable mercury ions in the treated polluted water to reach mercury discharge limit value 0.5mug/l. In the invention, the process is simple, organic mercury and inorganic mercury in the polluted water can be thoroughly removed effectively, so as to enable the mercury-containing concentration to reach emission standards.

The invention relates to the field of sewage treatment unitization, in particular to a method for reducing pollution of mercury and pesticide residue in sewage. The method can effectively eliminate the pollution of the mercury in the sewage, the method has the advantages of being high in efficiency, low in nutritional requirement, simple in operation and high in safety, compared with existing other technologies, the cost of pollution treatment on the mercury and the pesticide residue in the sewage is obviously reduced, the efficiency of pollution treatment on the mercury and the pesticide residue in the sewage is improved, and the very important practical application value is achieved.

The invention provides a solidification and stabilization method for mercury in mercury contaminants. The method includes the following steps that (1) mercury contaminant particles with the grain diameter not larger than 5 mm are mixed with soluble sulfide and water, and a first mixture is obtained; (2) the first mixture, cement and water are stirred and mixed, the stirring speed ranges from 20 r/min to 40 r/min, and a second mixture is obtained; and (3), after the second mixture is placed, the treated mercury contaminants are obtained. According to the method, the solidification effect of mercury in the contaminants is enhanced, the cement use amount is reduced on a large scale, the solidification capacity-increase ratio is small, and ready-made construction is rapid; and the leaching concentration of mercury after solidified bodies are stabilized for a long time is low, the mechanical strength of the solidified bodies can meet the requirements of ordinary road paving, and the solidification and stabilization method is suitable for mercury contamination repair projects with the large area, the tight schedule, the simple construction conditions and the low one-time invested cost requirement.

The invention discloses a normal-temperature and normal-pressure preparation method and application of a metal selenide mercury adsorbent. The metal selenide mercury adsorbent is prepared at normal temperature and normal pressure by adopting a precipitation method. The metal selenide mercury adsorbent comprises a compound formed by selenium and one or more of chromium, manganese, iron, copper, cobalt, nickel, zinc, molybdenum, silver and cadmium and a composite of the compound, unstable mercury is converted into stable mercury selenide, mercury in industrial tail gas or by-products of fire coal, metallurgy, waste incineration, cement production and the like is removed, mercury enriched in mercury-containing articles for daily use is absorbed, the recovery and reutilization of mercury resources are realized, and mercury to be treated can exist in the forms of a simple substance state, a free state and/or a compound state and the like. As the metal selenide has extremely high mercury adsorption capacity and adsorption rate, realization of large-scale preparation of the metal selenide under normal temperature and pressure conditions has great significance on mercury pollution prevention and control, and the corresponding technology has wide market application prospects.

A porous material, including metal organic frameworks (MOFs) and porous organic polymer (POP), with reactivity with or sorptive affinity towards (a) electronic gas to substantially remove or abate electronic gas in an electronic gas-containing effluent, or (b) contaminants in a stream of electronic gas to substantially remove the contaminants from a stream of electronic gas and increase the purity of said electronic gas, or (c) trace mercury contaminant in a hydrocarbon stream to substantially remove said mercury contaminant and increase the purity of said hydrocarbon stream. MOFs are the coordination product of metal ions and multidentate organic ligands, whereas POPs are the product of polymerization between organic monomers.

Methods and apparatus relate to treatment of fluids to remove mercury contaminants in the fluid. Contact of the fluid with an amine that has absorbed a sulfur compound causes the mercury contaminants to be absorbed by the amine. Phase separation then removes from the fluid the amine loaded with the mercury contaminants such that a treated product remains.

The invention discloses a method suitable for controlling mercury contamination in coal-fired power plants adopting wet-process flue gas desulfurization. The method is characterized in that halide additive solution is added into a boiler body to participate in combustion reaction so as to promote oxidization of mercury in flue gas and improve the proportion of mercury oxide in the flue gas; and sulfur-contained additive solution enters a desulfurizing tower and reacts with the flue gas or mercury oxide in size to produce mercuric sulfide precipitation or flocculent complex, and finally mercury in the flue gas of the coal-fired power plants can be effectively removed, wherein a sulfur-contained additive solution storage tank is arranged on the side of a wet-process flue gas desulfurization system and communicated with at least one of a fresh size pipeline of a desulfurizing tower and an inlet and an outlet of a circulating pump of the desulfurizing tower. The method has the advantages of low investment and running cost of a mercury contamination control system while ensuring that the emission level of mercury contaminations in the coal-fired power plants meets stricter environmental protection standard requirements; and as the wet-process flue gas desulfurization system is widely adopted in the coal-fired power plants in China, the method is wide in applicability.

The invention discloses a fly ash modification method used for mercury contamination in situ soil remediation, and applications. The method includes the following steps: (1) the step of acid modification, namely the step of preparing fly ash into slurry with a certain mass concentration under normal temperature, and adding sulfuric acid and hydrochloric acid with a certain concentration to performmodification; (2) the step of washing, namely the step of filtering the fly ash slurry obtained by the step (1), performing washing with clear water until a pH value is 7, and performing filtering for later use; (3) the step of combined modification, namely the step of preparing the washed fly ash into the slurry with a certain mass concentration, and adding phosphate, hydrogen peroxide and manganese dioxide to perform full stirring; and (4) the step of drying, namely the step of filtering the fly ash obtained by the step (3), and obtaining modified fly ash through drying. Mercury can be passivated by adding the modified fly ash into mercury-contaminated soil, so that the purpose of soil remediation can be achieved. As the fly ash can be adopted as a main material of mercury-contaminatedsoil remediation, the method can have advantages of being wide in raw material source and low in cost, and other heavy metal can be passivated as well.

The invention relates to the field of water treatment, and in particular relates to a treatment method of water polluted by mercury. The method comprises the following steps: (1) regulating the pH value of mercury-containing sewage to be 6-6.5, and adding sodium alcohol ether sulfate and sodium hypochlorite into the mercury-containing sewage, wherein the additive amount of sodium alcohol ether sulfate accounts for 1-2 times of the mass concentration of mercury in the sewage, and the additive amount of sodium hypochlorite accounts for 3-5 times of the mass concentration of mercury in the sewage; (2) regulating the pH value of the sewage to be 8-9, and then adding poly p-tert-butylphenol disulfide, ferrous sulfide and sodium hydrogen sulfate into the sewage under the conditions that the mass ratio of p-tert-butylphenol disulfide to ferrous sulfide to sodium hydrogen sulfate is (1-2) to (2-4) to 5, and the mass concentration of poly p-tert-butylphenol disulfide in the sewage is 1-5%; (3) then adding a flocculating agent, calcium oxide and alkylphenol polyoxyethylene into the sewage under the conditions that the mass ratio of the flocculating agent to calcium oxide to alkylphenol polyoxyethylene is 1 to 3 to 2, and the additive quantity of the flocculating agent is 0.1-0.3% of the quantity of the sewage; (4) standing the sewage for 3-5 days in a separation tank, and then performing solid-liquid separation; (5) adsorbing the separated sewage by adopting an activated carbon absorber, and then discharging the sewage.

The invention relates to a method for applying a phosphate fertilizer to reduce the content of mercury in rice grains of a heavy mercury polluted rice field, belonging to the technical field of agricultural product heavy metal pollution prevention and treatment. The method is characterized by comprising the following steps: in the heavy mercury polluted rice field (the soil Hg concentration is 2mg/kg, which is 4 times the national limit standard), applying 100kg/hm<2> (at a middle phosphorus application level by an effective component P2O5) of the phosphate fertilizer for three times, namely, applying 1/2 of the total phosphatic fertilizer 3 days before rice transplanting, and applying 1/4 of the total phosphatic fertilizer 5 days before earing and 10 days after head sprouting respectively; throwing the phosphate fertilizer 3 days before rice transplanting, namely, uniformly throwing the phosphate fertilizer into the rice field; applying the phosphate fertilizer in a leaf surface spraying mode 5 days before earing and 10 days after head sprouting, dissolving a water-soluble phosphate fertilizer into water, and spraying 300L of water with the phosphate fertilizer to each hectare of the rice field. Compared with a common high-level one-time phosphate fertilizer application method used in practical rice production, the method has an application effect that the content of mercury in the rice grains can be greatly reduced (the content of the mercury in indica type rice is reduced by 61.54%, and the content of mercury in japonica rice is reduced by 56.67%), and the yield of rice is not greatly reduced.

The invention discloses an attapulgite clay-thiocoumarin functional hybrid material, which is characterized in that it is prepared by hybridizing a thiocoumarin fluorescent dye having a molecular sizematching the size of an attapulgite clay pore, and the attapulgite clay under a certain condition; the material can be subjected to a specific selective fluorescence reaction with mercury ions, so that the fluorescence intensity at a certain wavelength is significantly improved; further, the material can produce an eye-recognizable color reaction so as to be used in the detection of mercury ionsto detect mercury contamination in water. The invention also discloses a method for preparing the attapulgite clay-thiocoumarin functional hybrid material, comprising an attapulgite clay preprocessingstep and a wet hybridization step. The processed attapulgite clay has a greatly increased specific area. The isopropyl alcohol wet hybridization can effectively promote the dissociation of the attapulgite clay and further promote the combination with the dye. The high-temperature baking promotes the dehydration of the attapulgite clay and promotes the hybridization of the thiocoumarin and the attapulgite clay.

The invention provides a mercury-polluted soil remediation agent and a preparation method thereof. The mercury-polluted soil remediation agent comprises clay mineral, and selenite and a sulfur-containing compound which are bonded on the clay mineral; wherein the clay mineral is montmorillonite and/or medical stone, and the sulfur-containing compound is a soluble sulfide and/or a sulfydryl-containing compound. The mercury-polluted soil remediation agent is prepared by a method of mixing and reacting various clay minerals, selenite and a sulfur-containing compound in a solvent. The selenium-containing remediation agent for mercury-polluted soil provided by the invention not only can improve the reduction effect of each component on the mercury content of crops, but also can reduce the enrichment capacity of the crops on selenium, and reduces the risk that the selenium of the crops is greatly increased due to the addition of selenium.

Provided is a method for preparing vinyl chloride with acetylene and dichlorethane for large-scale industrial production. Acetylene, dichlorethane vapor and hydrogen chloride gas at a molar ratio of 1:(0.3-1.0):(0-0.20) are mixed; the raw mixed gas is preheated; the preheated raw mixed gas passes through a reactor containing a catalyst and reacts; the resultant mixed gas is cooled to 30-50° C. and pressurized to 0.4-1.0 MPa, and then cooled to ambient temperature, and further frozen to −25-15° C. for liquefaction isolation, and unliquefied gas is recycled and reused; liquefied liquid is sent to a rectifying tower for rectification, and vinyl chloride monomers meeting polymerization requirements are obtained. The present invention has the advantages of eliminating mercury contamination completely, simplifying the reactor structure, recycling hydrogen chloride and acetylene, reducing waterwash process, avoiding mass production of waste acid and improving utilization of chlorine.

The present invention discloses a mercury-fibrinogen chelate, a preparation method therefor and an application thereof. The mercury-fibrinogen chelate is obtained by chelating mercury ions with a fibrinogen by a mercapto and/or cysteine residues. The present invention establishes a qualitative and quantitative detection method for the mercury-fibrinogen chelate, so as to quantitatively detect the mercury-fibrinogen chelate in the application of evaluating the mercury contamination degree of a specific region. By quantitatively detecting the mercury-fibrinogen chelate in human serum in the specific region, the mercury contamination influence on human bodies can be reflected indirectly, and the mercury contamination degree of the specific region can be reflected indirectly thereby. The quantitative detection method for the mercury-fibrinogen chelate established in the present invention has much higher accuracy and greatly improved detection repeatability.

The invention discloses a load plug-in of a superfine fiber electrostatic adsorption catalyst and a use method of the load plug-in. The load plug-in mainly comprises a mercuric chloride catalyzing particle, an electro-adsorption superfine fiber membrane layer, a catalyst load layer and a static isolating layer, the catalyst load layer covers the surface of the mercuric chloride catalyzing particle, the static isolating layer covers the surface of the catalyst load layer, the electro-adsorption superfine fiber membrane layer is wrapped on the outermost layer, and electro-adsorption superfine fiber membrane electric terminals are arranged at the two ends of a tube plate flange. In the use process, the plug-ins are sequentially arranged in a heat exchanger, the two ends of the tube plate flange are powered on with a direct current power supply, the electro-adsorption superfine fiber membrane electric terminals are arranged at the two ends of the tube plate flange, so that an electric conduction fiber membrane contains even electric charges, finally the mixed gases are introduced into the heat exchanger filled with the mercuric chloride catalyst plug-in, and the gases react with the catalyst when passing through catalyst plug-in. According to the load plug-in of the superfine fiber electrostatic adsorption catalyst and the use method of the load plug-in, the use efficiency of the catalyst is improved, the reaction speed is increased, and the mercury contamination and treatment are also reduced.

The invention discloses a treatment method for methyl mercury polluted water. The treatment method comprises the following steps: introducing water containing methyl mercury into a cationic resin exchanger, and stopping exchanging when the concentration of methyl mercury in a water solution flowing from the cationic resin exchanger is greater than 0.00005mg/L; taking out cationic resin, utilizing a saturated sodium chloride mixed liquor of 8-12% stannous chloride as regenerated liquid, and performing regeneration under a mixing condition, wherein the ratio of the regenerated liquid to the resin is (1-2) to 5, the mixing time is 40-60 minutes, and the temperature is 40-45 DEG C; separating the resin from mercury-containing liquid after regeneration is ended, returning the regenerated resin to the resin exchanger to recycle, and feeding the mercury-containing liquid into a sedimentation basin; adjusting the pH of the obtained mercury-containing liquid to be greater than 10 by using sodium hydroxide, and filtering the mercury-containing liquid to obtain mercury-containing sediments; smelting the mercury-containing sediments by using a smelting furnace at high temperature of 560 DEG C, recovering mercury vapor, and condensing the vapor, so as to obtain a metal mercury product. By adopting the treatment method, methyl mercury pollution in water can be removed, and the methyl mercury can be converted into metal mercury to recycle.

The invention discloses a method for safely utilizing mercury-contaminated soil. According to the method, the mercury-contaminated soil is reasonably and safely utilized and the remediation effect ofthe mercury-contaminated soil can be realized. The method specifically comprises the following steps: in mercury-contaminated farmlands in the Yangtze River basin, a crop rotation mode of planting oilseed rape in winter and planting oenothera biennis, or oil sunflower, or soybean, or peanut and other oil crops in summer is adopted, the mercury content of edible parts of crops is ensured to be in asafe range by utilizing the mercury element enrichment difference of different crops and the accumulation difference of mercury in the edible parts; meanwhile, the accumulation effect of non-edible parts (high biomass) of the selected crops on mercury is utilized, and the effect of removing and repairing mercury in soil is achieved. The method aims to ensure the edible safety of agricultural products while repairing the mercury-contaminated soil, improve the utilization and repair efficiency of the mercury-contaminated soil, relieve the conditions of shortage of cultivated land resources andsevere safety situation of grains and foods in China, and create good economic, social and ecological benefits.