The invention discloses an organic solar cell device and a preparation method thereof. The organic solar cell device comprises the components of an anode electrode layer, an anode interface modifying layer, a light active layer, a cathode interface modifying layer and a cathode electrode layer. The anode interface modifying layer and the cathode interface modifying layer are made of the same material which is a polymer that is represented by a formula I. In the formula I, A is a random material selected from sulfonic acid group, sodium sulfonate group, potassium sulfonate group, lithium sulfonate group, ammonium sulfonate group, sulphonylamino, carboxylic acid group, carboxylic acid ester group, sodium carboxylate group, potassium carboxylate group, lithium carboxylate group, ammonium carboxylate group and amide; R is an alkyl with 1-12 carbon atoms; Ar is a random member selected from the following unsubstituted or substituted group: single-ring arylene, double-ring arylene, three-ring arylene, arylene with more rings, single-ring heteroarylidene, double-ring heteroarylidene, three-ring heteroarylidene, heteroarylidene with more rings, and a group which is composed of 2-6 arylenes which are connected through single bonds; wherein n is selected from 2-500. The organic solar cell device and the preparation method have advantages of simplifying an optimization process and a manufacture process for the material of the interface modifying layers, and reducing the synthesis cost of the material.