62 results about "Sodium diphenylamine sulfonate" patented technology

The invention discloses an aluminium product chemical polishing solution composition with nitric acid free. The composition uses sulfuric acid and phosphoric acid as a basic solution, an additive is composed of aluminium sulphate (or aluminium nitrate), potassium permanganate, sodium nitrate, diphenylamine sulfonic acid sodium salt, tartaric acid and zinc sulfate. Polishing temperature is 110-150 DEG C, polishing time is 10s-120s when the polishing solution is used for polishing. The composition can ensure no nitrogen oxide yellow smoke harm, at the same time ensure the aluminium product having better polishing blare effect for reaching mirror surface brightness, and having little rate of weight loss.

The invention provides a method for rapidly determining the content of total iron in vanadium titano-magnetite. The method comprises the following steps: (1) weighing a to-be-determined vanadium titano-magnetite sample with the weight of M; (2) adding sufficient mineral dissolving solution to dissolve the to-be-determined vanadium titano-magnetite sample in a heating manner; (3) adding dilute hydrochloride acid into a reaction vessel; (4) dropwise adding stannous chloride solution to the reaction vessel until the mixed solution turns pale yellow, reheating the mixed solution to be boiled slightly, and cooling the mixed solution to the room temperature; (5) adding sodium tungstate solution into the reaction vessel, dropwise adding titanium trichloride solution until the mixed solution turns blue, and dropwise adding titanium trichloride solution to be slightly excessive in volume; (6) dropwise adding potassium dichromate solution into the reaction vessel until the mixed solution is colorless, and dropwise adding sodium diphenylaminesulfonate indicator; (7) titrating the mixed solution in the reaction vessel to be purple by adopting potassium dichromate standard titration solution; (8) sampling the solution after being titrated to be purple, and determining the weight percentage of vanadium in the sample; and (9) calculating. The method is easy to operate, high in determination speed, capable of enabling the detection result to be equivalent to that of a national standard method and capable of better meeting the in-situ rapid analysis requirement.

The invention discloses a method for synthesizing polypyrrole nano-particles with diphenylamine sulfoacid, its characters are as follow: it prepares the monomer solution with the pyrrole and diphenylamine sodium in the acidic solution in accordance with a molar ratio of 10:90 ~ 90:10, and then it adds the oxidant solution to the monomer solution for reaction. In which, the molar ratio of the pyrrole and diphenylamine sodium with the oxidizer are 1: 0.1 ~ 1.

The invention relates to a method for determining total iron in vanadium titano-magnetite by using an acid dissolution method. The method comprises the following steps: dissolving a sample with sulfuric acid-phosphate mixed acid; in a hydrochloric acid medium, using stannous chloride to reduce a great amount of ferric iron, using potassium permanganate to oxidize vanadium, using sodium tungstate as an indicator, using titanium trichloride to reduce ferric iron to diatomic iron, oxidizing excessive titanium trichloride with potassium dichromate until tungsten blue fades, using sodium diphenylaminesulfonate as an indicator, and determining the content of iron with potassium dichromate titration. Compared with determination with an alkali fusion method, the method greatly shortens the operating process, saves drugs, reduces human resource cost, and improves the production efficiency; as the potassium permanganate oxidation process is adopted, the interference of vanadium on iron is eliminated, the determination results are stable, and data is accurate.

The invention discloses a method for rapidly determining the content of total iron in nitrided ferrovanadium. The method comprises the steps of: 1, decomposing a nitrided ferrovanadium sample by an alkali fusion method to obtain an alkali fusion sample; 2, leaching the alkali fusion sample by hydrochloric acid, adding sodium hydroxide to a leaching solution for precipitation, and filtering and separating the solution to obtain a ferric hydroxide precipitate; 3, acidifying the ferric hydroxide participate by hydrochloric acid, heating the acidified precipitate to a boiling point, dropwise adding stannous chloride to the heated precipitate to reduce ferric iron into ferrous until the stannous chloride is excessive; and 4, oxidizing the excessive stannous chloride by mercuric chloride, titrating the oxidized stannous chloride by a potassium dichromate standard solution with sodium diphenylaminesulfonate being an indicator, thus calculating the content of the total iron of the nitrided ferrovanadium sample. The method is capable of separating vanadium and ferrum and eliminating interference of high vanadium to determination of the total iron, thereby ensuring the accuracy of a determination result. The method is used for directly determining the content of the total iron in the nitrided ferrovanadium, the detection time is shortened from original 10h to 1h, and the detection speed is greatly enhanced. The method has the characteristics of being direct, simple, convenient and feasible.

The invention belongs to the field of two-dimensional nano materials and preparation thereof, and particularly relates to a preparation method of graphene. The method is characterized by comprising the following steps: adding a reducer into a graphite oxide dispersion liquid, heating to react, and carrying out centrifugal separation to obtain the graphene, wherein the reducer is sodium diphenylamine sulfonate. The method has the advantages of more sufficient reduction of graphite oxide, easy product separation and simple purification process. In the preparation process, no stabilizer or dispersant is added, and the obtained graphene contains fewer impurity elements; and the invention has the characteristics of controllable process, short period, atmospheric conditions, simple equipment and excellent graphene properties, is suitable for industrial production, and has wide application prospects in the technical fields of catalysis, energy transfer and storage, sensors and the like.

The invention discloses an analytic method for measuring the content of each component in a sulfuric acid and nitric acid mixture. The method comprises the following steps: firstly measuring the total acidity of the mixture by adopting an acid-base titration method; subsequently measuring the content of nitric acid by adopting an oxidation-reduction titration method, wherein discoloration sensitivity is improved by adding an auxiliary indicator such as sodium diphenylaminesulfonate so as to correctly judge a titration end point; finally calculating the difference value to obtain the content of the sulfuric acid. The method has the advantages of simple detection requirements and conditions, low detection cost, high sensitivity, accurate and reliable results and the like.

The invention relates to a method for measuring the iron content of a lithium iron phosphorous oxide iron source raw material of a lithium ion power battery anode material. The method comprises the following steps: placing an iron salt raw material into a muffle furnace for high-temperature calcinations; heating and dissolving a calcined product by using concentrated hydrochloric acid; adding a proper amount of deionized water to adjust the acidity of a solution; continuously heating the solution till boiling; adding a few drops of methyl hesperidin indicators; adding a high-concentration stannous chloride solution until the solution becomes straw yellow; slowly and dropwise adding a low-concentration stannous chloride solution until the solution becomes pink; and shaking uniformly to obtain a colorless transparent solution; quickly cooling; adding a proper amount of sulfur-phosphorus mixture acid; dropwise adding a few drops of sodium diphenylaminesulfonate indicators; and titrating a potassium dichromate standard solution, and completing a reaction process when the solution is changed from blue-green into purple. The method is convenient to operate and easy to control in the whole process and accurate in the test result. Compared with the conventional method, the method has the advantages that mercury salt is not adopted, so the health of operation staff is not damaged, the environment pollution is avoided, and the method is suitable for testing of the lithium iron phosphorous oxide iron source raw material of the lithium ion power battery anode material.

The invention relates to a method for determining iron, aluminium and silicon in silica simultaneously. The method comprises the following steps that a silica sample is burned to reach the constant, hydrofluoric acid and nitric acid are added for dissolving, silicon is removed through evaporation to dryness and volatilization, and fluorine is expelled with nitric acid; burning is conducted to reach the constant at 1,050+/-50 DEG C, and the difference between two weighing is the silicon dioxide quantity; residues obtained after silicon dioxide is determined is fused with a mixed solvent, leaching is conducted with diluted hydrochloric acid, a leaching solution is neutralized with ammonium hydroxide, high valence metal ions are made to form hydroxide precipitates, burning is conducted, and sesquioxide is generated and weighed; precipitates determining sesquioxide is fused with potassium pyrosulfate, after leaching and dissolving are conducted with hydrochloric acid, reduction is conducted with stannous chloride to reach light yellow, sodium tungstate serves as an indicator, residual ferric iron is reduced with titanium trichloride, at last, sodium diphenylamine sulfonate serves as anindicator, titration is conducted with a potassium dichromate standard titration solution, and the content of iron sesquioxide is measured. The determination method has the advantages of being shortin operation procedure, high in efficiency and stable and accurate in result.

The invention relates to a continuous determination method of sodium nitrite-potassium nitrate mixed salt in a salt bath, which is mainly technically characterized by firstly heating sample solution of the sodium nitrite-potassium nitrate mixed salt to a certain temperature, using potassium permanganate standard solution for titration under appropriate acidity, and utilizing the quantitative reaction of sodium nitrite and the potassium permanganate standard solution to calculate the content of the sodium nitrite in the sample solution; further acidifying the sample solution, adding excess ferrous ammonium sulphate standard solution, heating till boiling, keeping for 2-4 minutes, cooing to normal temperature, then sequentially adding water, phosphoric acid solution and sodium diphenylamine sulfonate indicator solution, using the potassium permanganate standard solution for titration, obtaining the volume of the potassium permanganate standard solution consumed by the sample solution, simultaneously carrying out a blank test, obtaining the volume of the potassium permanganate standard solution consume in the blank test, and further calculating the content of potassium nitrate in the sample solution. The method can detect the change situation of components in the salt bath and prevent the components in the salt bath from aging, and has the characteristics of simple method, rapidness, low cost, high accuracy and the like.

The invention discloses a novel method for determination of total iron of iron ore by a potassium dichromate volumetric method. The novel method comprises the following steps of crushing an iron ore sample to obtain powder having particle size less than 0.088mm, weighing 0.1000g of the crushed iron ore sample, putting the crushed iron ore sample into 250mL of a conical flask, adding 6mL of concentrated hydrochloric acid into the conical flask, carrying out heating dissolution, dropwisely adding a tin dichloride solution into the conical flask until the color is white, carrying out cooling, fast adding 100mL of tap water into the conical flask, adding 5ml of a sulfur-phosphor acid mixture standard solution into the conical flask, dropwisely adding 4 drops of a sodium diphenylaminesulfonate indicator into the conical flask, and carrying out titration by a potassium dichromate standard solution until the color is purple. The novel method reduces a reagent use amount by 1/2, is free of titanium trichloride and sodium tungstate and utilizes tap water to replace distilled water or deionized water. The novel method furthest reduces reagent and energy consumption and a lab test cost, reduces environmental pollution, reduces labor intensity of lab test workers, improves a lab test speed and reduces iron ore sample lab test time to about 3min from about 10min.

A method for determination of iron in a copper alloy comprises the following steps: (1) a copper alloy sample is weighed and put into a conical flask, and HCl and H2O2 are used for heating to dissolve the sample; (2) the copper alloy sample solution is taken and slightly cooled, an ammonia solution is used to adjust pH value to 6.8-7.2, the copper alloy sample solution is filtered and washed with the ammonia water until the copper alloy sample solution is free of copper ions, and hydrochloric acid is used for washing a precipitate into a conical flask; (3) tin dichloride is used for reduction of the solution to yellowish; then water is added, a mixed acid of phosphoric acid and sulfuric acid is added, a few drops of a sodium tungstate indicator are added, and a titanium trichloride solution is added dropwise until the solution is blue; then a potassium dichromate standard titration solution is used for titration of the solution until the blue color disappears; then three drops of a sodium diphenylaminesulfonate indicator are added, and the potassium dichromate standard titration solution is used for titration of the solution until a stable purple color as the end point is reached. The reaction speed is fast, the end point is stable, does not change color and is easy to observe, and the accuracy is good; meanwhile the determination process is short, determination efficiency is high, the determination method is easy to grasp, used chemicals are simple, and the method has the advantages of low pollution, low requirements for equipment and environment and low determination cost.

The invention provides a method for detecting content of total iron in vanadium titanium powder, characterized in that the detection method comprises following steps: (1) weighing a sample of the vanadium titanium powder to be detected and placing it in a container, adding sulfur and phosphorus mixed acid, and dissolving to obtain mixed solution; (2) adding concentrated hydrochloric acid to the mixed solution prepared in the step (1), boiling, dropping stannous chloride solution until pale yellow solution is obtained, using sodium tungstate solution as an indicator, dropping titanium trichloride solution until the solution turns light blue, and then dropping a drop of the titanium trichloride solution to obtain blue solution; (3) adding copper sulfate solution for catalysis to the blue solution prepared in the step (2) to obtain colorless solution; and (4) using sodium diphenylamine sulfonate solution as the indicator, dropping potassium dichromate standard solution to the colorless solution obtained in the step (3) until the solution turns light purple as an endpoint.

The invention discloses a method for determining the content of metallic magnesium in a briquetting nodulizer through a subtraction process. The method comprises the following steps: dissolving metallic magnesium in a sample by dilute acetic acid, filtering, washing, drying a insoluble substance, and weighing; transferring a certain volume of a filtrate, completely reducing ferric iron to divalent iron by titanium trichloride with sodium tungstate as an indicator until tungsten blue is generated, oxidizing the above excess reducing agent by a dilute potassium dichromate solution, tiltrating divalent iron by a potassium dichromate standard solution in a sulfuric acid-phosphoric acid medium with sodium diphenylamine-sulfonate as an indicator, and calculating the mass fraction of iron in the filtrate; and subtracting the mass fraction of iron in the filtrate from the mass fraction reduced to the dissolving by the dilute acetic acid in the sample. The method has the advantages of simplicity, rapidness, high accuracy, high precision and the like, and fully meets the requirements of metallurgical furnace laboratory analysis.

The invention discloses a measurement method for iron content in iron-copper-tin ternary prealloy powder. In hydrochloric acid solution, Fe3<+> is recovered into Fe<2+> by using SnCl2, then HgCl2 is added to oxidize the excess SnCl2, sodium diphenylaminesulfonate is used as an indicator, and potassium dichromate standard solution is used for titration. The method provided by the invention can be quick in measurement, and accurate in measurement result.

The invention discloses a calibration method of a potassium dichromate standard solution. The calibration method comprises the following steps that S1, a pure iron sample is weighed and is placed in aconical flask, hydrochloric acid and concentrated nitric acid are added slowly; S2, the conical flask is boiled at low temperature, a stannous chloride solution and the hydrochloric acid are continuously added dropwise; S3, the conical flasks cools; S4, water and a sodium tungstate dihydrate solution are added in the conical flask, and a titanium trichloride solution is added dropwise; S5, the standard solution is added dropwise in the conical flask until blue disappears, sulphuric acid-phosphoric acid mixed acid is added immediately, and a diphenylaminesulfonic acid sodium salt indicator solution are added; S6, the potassium dichromate standard solution is titrated into the conical flask until the solution in the conical flask turns into blue-green from green, when the last drop shows astable purple, titration is completed, and the volume V of the potassium dichromate standard solution consumed by titration is recorded; and S7, according to the addition quantity, molar concentrationof the potassium dichromate standard solution can be calculated. The method is accurate in calibration, and is simple and easy to master.

The invention discloses a raspberry drop irrigation fertilizer which comprises the following components in percentage by mass: 15-28 percent of sodium diphenylamine sulfonate, 15-20 percent of auxiliary fertilizers, 1-3 percent of vitamins, 0.1-0.5 percent of amino acids, 2-4 percent of humic acid, 0.1-0.5 percent of alkaloid and the other components of purified water. According to the raspberry drop irrigation fertilizer disclosed by the invention, the defects that the conventional drop irrigation fertilizer adopts a single nutritional ingredient and contains harmful substances and drop irrigation equipment is easily blocked are overcome, and the advantages of comprehensive nutrition, no toxicity, high solubility and the effects of not blocking the pipeline and saving the production cost are realized.

The invention discloses a method for measuring the concentration of total-iron ion in chemical cleaning solution containing a strong complex. A principle is as follows: in an acidic condition, silversulphate is a catalyst; a strong complex substance is oxidized by ammonium persulfate and hydrogen peroxide, so that the complexation to iron ion is lost; furthermore, divalent iron is converted intoferric iron; ferric iron is reduced to divalent iron through stannous chloride; excess stannous chloride is oxidized by mercury bichloride; finally, sodium diphenylaminesulfonate is used as an indicator; and the reduced divalent iron is oxidized by potassium bichromate. The method is simple and rapid to operate and high in sensitivity and accuracy; measurement can be carried out by a conventionalanalysis vessel; the measurement time for one time is not beyond 25 min; the detection limit is 10 mg/L; the recovery rate is 92.5-107.3%; the detection range is 100-12000 mg/L; and test requirementsin a chemical cleaning field can be completely satisfied.

The invention discloses a chemical copper plating solution and a method for chemical copper plating. The chemical copper plating solution comprises the components including, by mass concentration, a main salt, a reducing agent, a complexing agent, a stabilizer, an accelerator, a surfactant and the balance ultrapure water. The chemical copper plating solution further comprises a pH value regulator and an additive, wherein the additive is polyvinylpyrrolidone and sodium diphenylaminesulfonate. The chemical copper plating method comprises the steps of alkaline oil removal, micro-etching, preimpregnation, activation, peptization and copper deposition. Alkaline oil removal, micro-etching, preimpregnation, activation and peptization are pretreatment procedures to adsorb colloidal palladium particles to a PCB to be plated with copper. In the copper deposition process, copper ions are catalytically reduced to the PCB to be plated with copper through the chemical copper plating solution. In the chemical copper plating solution, the polyvinylpyrrolidone and the sodium diphenylaminesulfonate are used as the combined additive, so that the chemical copper plating solution has the characteristics of being environmentally friendly, low in price and easy to obtain, and the copper plating effect can be effectively improved while the copper plating rate is ensured.