The invention discloses a voltage optimization method of an electric-field coupling type wireless charging technology of an electromobile, and relates to the technical field of electric-field couplingtype wireless charging. A direct current power supply, a high-frequency inverter, a primary edge compensation structure, a coupling structure, a secondary edge compensation structure, a high-frequency rectifier and a load which are successively connected are involved. The coupling structure comprises a simulation ground, a simulation electromobile shell and a coupling pole plate set, the couplingpole plate set comprises two transmitting pole plates and two receiving pole plates, and every two of the transmitting pole plates, the receiving pole plates, the simulation ground and the simulationelectromobile shell form a capacitor. The method comprises the steps that firstly, parameters, input voltages, output voltages and output powers of all the capacitors among the pole plates in the system are determined, then the system frequency v is selected, the system frequency v is compared with the lowest system frequency fmin obtained from calculation of the parameters, the system frequencyv is determined, inductance values of all transmitting coils and receiving coils are calculated, and based on the calculated inductance values, the transmitting coils and the receiving coils are manufactured to construct a CPT system circuit.