The invention relates to a method for selectively determining residual
vinyl acetate in white latex for cigarette through static headspace and
gas chromatography mass spectrometry, belonging to the technical field of physical and chemical inspection of materials for the cigarette, and provides a quantitative selected
ion determining method through the static headspace and
gas chromatography mass spectrometry, aiming at selectively determining the residual
vinyl acetate in white latex for the cigarette. A sample of the white latex for the cigarette after static headspace at 80 DEG C for 15 minutes is detected by taking 2-hexanone as an
internal standard through HP-INNOWAX column in a GC-MS / SIM (
Gas Chromatography Mass Spectrometry /
Selected Ion Monitoring) mode, and is quantified through an
internal standard method. According to the method for selectively determining the residual
vinyl acetate in the white latex for the cigarette through the static headspace
gas chromatography mass spectrometry, disclosed by the invention,
detection limit, labeling
recovery ratio and RSD (
Relative Standard Deviation) of the method are respectively 0.63mg / kg, 104-107% and 2.5-4.9%; in addition, the method disclosed by the invention has the characteristics of simpleness, fastness, accuracy, sensitiveness and the like, and is especially suitable for quantitative analysis on the residual vinyl acetate in the white latex for the cigarette.