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Pyrolysis device and method for in-situ conversion of carbon-containing resources by microwave-assisted pyrolysis

ActiveCN102718383ASolve the difficulty of large-scale collectionSolve the inconvenience of storage and transportationSludge treatment by pyrolysisByproduct vaporizationSlagChar
The invention discloses a pyrolysis device for in-situ conversion of carbon-containing resources by microwave-assisted pyrolysis. The device comprises a microwave-assisted pyrolysis reactor, a solid outlet of the reactor is connected with an inlet of a pyrolytic carbon cooler, an outlet of the pyrolytic carbon cooler is connected with a slag storer through a deslagging machine, a gas outlet of the reactor is connected with an inlet of a condenser through a pipeline, the condenser is provided with a gas-liquid separator, a gas outlet of the condenser is connected with a gas purifier, an outlet of the gas purifier is connected with a gas compressor, a liquid outlet of the condenser is connected with a liquid circulating pump, then one branch of the condenser is connected with an oil storage tank, and the other branch of the condenser is connected back to the condenser through a cooling medium circulating system. The invention further discloses a method for the in-situ conversion of the carbon-containing resources by the microwave-assisted pyrolysis. By the pyrolysis device and the method for the in-situ conversion of the carbon-containing resources by the microwave-assisted pyrolysis, various low-grade carbon-containing resources can be collected, stored and continuously produced at an economic scale.
Owner:SHANGHAI ADVANCED RES INST CHINESE ACADEMY OF SCI

Technology and device for removing hydrogen and nitrogen from methane rich gas and producing liquefied natural gas

The invention discloses a technology and a device for removing hydrogen, nitrogen and carbon monoxide from methane rich gas and producing liquefied natural gas (LNG). The technology comprises two parts, namely low-temperature liquefaction and rectification separation after flash evaporation; the low-temperature liquefaction part is finished in a cold box by using cold flow supplied by a mixed refrigerant; in the rectification separation part after flash evaporation, the hydrogen, the nitrogen and the carbon monoxide are removed by adopting a flash evaporation and rectification flow; and after the methane rich mixed gas containing the hydrogen and the nitrogen sequentially passes through the cold box, a re-boiler at the bottom of a rectification tower and the cold box and the methane components are liquefied, the methane rich mixed gas enters a rectification separation system, and the hydrogen, the nitrogen and the carbon monoxide are removed, wherein the obtained LNG product contains less than or equal to 2,000ppm of hydrogen, less than or equal to 4 percent of nitrogen and less than or equal to 6 percent of carbon monoxide. By the natural gas liquefaction technology for the methane rich gas containing the hydrogen, the nitrogen and the carbon monoxide, the hydrogen, the nitrogen and the carbon monoxide are removed, and the LNG is obtained at the same time; the technology is advanced in process route; and compared with the conventional technology, the technology has the advantage that the investment cost of equipment and the energy consumption of the system are remarkably reduced.
Owner:XINDI ENERGY ENG TECH +1

Heavy hydrocarbon removing process and device of natural gas

The invention relates to a heavy hydrocarbon removing process of natural gas, i.e. a heavy hydrocarbon removing process by adopting the combination of an adsorbent and low-temperature separation. According to the heavy hydrocarbon removing process disclosed by the invention, most heavy hydrocarbons in the natural gas are removed by an adsorbent bed layer of a heavy hydrocarbon removing tower, then the natural gas enters a cold box for further low-temperature separation to remove residual heavy hydrocarbons, and C6 and C6<+> heavy hydrocarbon components in the natural gas after treating are removed until the soluble degree of LNG (Liquefied Natural Gas); regeneration gas used for regeneration of the heavy hydrocarbon removing tower is taken from process gas, and is regenerated by sequentially pre-cooling, partial heavy hydrocarbon separation and low-temperature heavy hydrocarbon separation in the cold box, so that excessive heavy hydrocarbons are not carried when the regeneration gas is returned to the process gas, the load of the heavy hydrocarbon removing tower and the device investment cost are lowered, and the source and destination problems of the regeneration gas are solved. In addition, with the adoption of the heavy hydrocarbon removing process, the purification effect is good, and an operation index of each part is clearer and is easily controlled. The invention also relates to a device used by the process.
Owner:XINDI ENERGY ENG TECH

Method for preparing isocyanate monomer

The invention discloses a method for preparing an isocyanate monomer. The method comprises the following steps: adding a first batch of solvents in a reaction kettle and circulating; compressing HCl, conveying HCl in a salt-forming reaction kettle through the outer tube of a mixer, carrying out gas-liquid separation and then circulating HCl in a system through a Venturi mixer; mixing diamine with the residual solvents in the inner tube of the mixer, then mixing the mixture with HCl in the outer tube, and then conveying the mixture in the salt-forming reaction kettle and reacting to obtain a diamine hydrochloride solution; reacting the diamine hydrochloride solution with phosgene under a pressurization condition to obtain an isocyanate photochemical solution. The mixer comprises the inner tube and the outer tube, wherein a spiral plate is installed in the thick-diameter part of the inner tube, a hole is formed in the tube wall of the thin-diameter part of the inner tube, and the bottom of the inner tube is a detachable bottom plate; the outer tube sleeves outside the inner tube, and the bottom of the outer tube is a mixer outlet. The method disclosed by the invention reinforces the mixing effect of the gas-liquid reaction, the obtained hydrochloride particles are uniform, the use efficiency of HCl is high, the energy consumption is low, and the purity of the photochemical solution after a phosgenation reaction is high.
Owner:WANHUA CHEM GRP CO LTD +1

Complexing centrifugal extraction method of high-concentration phenolic wastewater

InactiveCN101723528ALarge extraction and dephenolization coefficientForward and reverse reactions are easyWater contaminantsMultistage water/sewage treatmentHigh concentrationWastewater
The invention provides a complexing centrifugal extraction method of high-concentration phenolic wastewater, which utilizes an efficient extractor and a back wash extractor to process high-concentration phenolic wastewater. The method of the invention comprises the following steps: 1) pretreating the phenolic wastewater; 2) leading the extracting agent to flow to each extractor in turn; 3) leading the phenolic wastewater to flow reversely into each extractor which is flown with extracting agent for extraction reaction; 4) discharging the wastewater from the extractor after dephenolizing; 5) discharging the extracting agent rich in phenol from the extractor which is filled with wastewater firstly; 6) leading the extracting agent rich in phenol to flow reversely to each back wash extractor, leading the thin alkali solution to flow into each back wash extractor which is flown with extracting agent rich in phenol for backextraction reaction; and 7) discharging the phenolate generated in the backextraction reaction from the back wash extractor which is flown with extracting agent rich in phenol firstly, and discharging the extracting agent after backextraction from the back wash extractor which is flown with thin alkali solution. The invention has low cost, small floor area, great flexibility of device operation, low consumption, the phenol content of the processed water is reduced to below 200ppm, the phenol removal rate is above 99%, thus achieving the biochemical treatment water quality standard, recovering the phenol in the waste water in the form of phenolate to return to the system for reuse, and lowering environmental pollution.
Owner:山西焦化股份有限公司

Gas phase SO3 film-scrapping sulfonating technology

The invention relates to a gas phase SO3 film-scraping sulfonating technology which belongs to the technical field of production technology which prepares anionic surfactant by using gas phase SO3 film-scraping sulfonating liquid organic materials. The invention is carried out according to the following steps: A: liquid SO3 is vaporized to gas phase SO3, the gas phase SO3 is sucked in a mixer shaft through a turbo-blower, the gas phase SO3 is mixed with inert gases recycled in a sulfonating reactor to reaction gas with the volume concentration being 0.1 to 10 percent, and then the reaction gas goes into a reaction cylinder body through reaction gas distribution holes on the upper part of the scraping plate shaft; B: the organic materials go into the sulfonating reactor and downwards flow along the inner wall of the reaction cylinder body, a scraping plate is rotated along with the mixer shaft under the action of a transmission system, the organic materials are continuously suffered with film scaping-spread coating-film scaping in the inner wall of the reaction cylinder body, the organic material are alternately updated and uniformly coated on the inner wall of the reaction cylinder body, and the organic materials are completely contacted and reacted with the reaction gas which goes from the reaction gas distribution holes to form reaction products. The design of the technology is reasonable, and the invention can be suitable for sulfonating or sulphating materials with various viscosities.
Owner:ZANYU TECH GRP CO LTD

Device and process for removing hydrogen sulfide contained in industrial gas

The invention belongs to the technical field of removal of hydrogen sulfide contained in gases, and particularly relates to a device and a process for removing the hydrogen sulfide contained in an industrial gas, aiming at providing high-efficiency rotating packed bed equipment applicable to occasions with large flux and high treatment requirements. The device comprises a rotating packed bed and a regeneration system, wherein the liquid inlet pipe of the rotating packed bed is connected with a barren solution tank through a barren solution pump, and an air inlet pipe is connected with a sulfurous gas; the liquid discharge pipe of the rotating packed bed is connected with a pregnant solution tank, and an air outlet pipe is connected with a demister. The process comprises the following steps: preparing a desulfurizing solution; respectively introducing the desulfurizing solution and the gas which contains the hydrogen sulfide into the rotating packed bed; introducing a liquid discharged from the rotating packed bed into the regeneration system for recovery. The device and the process which are disclosed by the invention have the advantages of good desulfurization effect, small occupied area, high mass transfer efficiency, small liquid circulating amount, small gas-phase pressure drop, low operation cost and convenience for start and stop. According to the invention, the integral process system can be stable within a few minutes.
Owner:ZHONGBEI UNIV

Method and equipment for preparing aromatic sulfonic acid by gas-phase sulphonation of aromatic organic compound

The invention relates to a method and equipment for preparing aromatic sulfonic acid by the gas-phase sulfuric anhydride sulphonation of aromatic organic compounds with a rotating packed bed. The method solves the problems of the existing method in which the aromatic sulfonic acid is prepared by the sulphonation of aromatic organic compounds using sulfuric anhydride gas as sulphonating agent. The method is as follows: the aromatic organic compounds and the mixed sulfuric anhydride gas enter the started rotating packed bed and come into contact to produce partial sulphonation reaction; the liquid product after reaction enters a tubular heat exchanger and the reaction proceeds; and the aromatic sulfonic acid is obtained. The equipment comprises the rotating packed bed; the liquid inlet of the rotating packed bed is connected with a raw material storage tank; the gas inlet of the rotating packed bed is connected with the mixed sulfuric anhydride gas source; and the liquid outlet of the rotating packed bed is connected with a product storage tank through the tubular heat exchanger. The invention has the advantages of easy control of reaction temperature, reduction of the possibility of subsidiary reaction, enhancement of reactive selectivity, avoidance of environmental pollution, energy saving, small equipment volume, light weight, convenient installation and maintenance, and convenient starting and shutdown.
Owner:ZHONGBEI UNIV

Device and method for continuously back extracting penicillin

The present invention relates to an equipment and the operation method for continuous penicillin stripping. An extraction tower is controlled by a computer control system; a cylindrical tower reaction extraction section adopts a jacketed structure; a clarification section container on the upper end of the tower body is larger than a clarification section container on the lower end of the tower body; a tower body extension section that extends into the upper clarification section container is bended outwards after a certain length of extension; a reflux hole is arranged on a straight tower body on the tower body extension section; an arc-shaped baffle plate with a downward arc core is arranged over the tower body extension section; a central shaft with a tower plate enters into the top of the upper clarification section container to make the bottom of the central shaft landed in a central shaft slot; a light phase distributor, a pH meter probe and a light phase in a heavy phase clarification area are arranged in the lower clarification section container; a laser particle size analyzer is arranged on a flange which connects the upper clarification section container with the tower body; a polarimeter is arranged on a pipe on an organic extraction raffinate phase exit. The invention can effectively inhibit the problems of penicillin degradation and milk slag handling, which can be applied to large-scale penicillin production through on-line automation control.
Owner:INST OF PROCESS ENG CHINESE ACAD OF SCI

Device and method for removing methanol from methyl tert-butyl ether cracking product

The invention discloses a device and a method for removing methanol from a methyl tert-butyl ether cracking product. The MTBE cracking product and absorption liquid undergo cross flow-counterflow contact in a multistage airflow shear cross-flow bed; under the shear action of high-speed rotating filler, cracked gas and the absorption liquid are dispersed, coalesced and redispersed for multiple times, so that multistage absorption is realized; cracking gas is introduced to a gas inlet in the side bottom of a multistage airflow shear cross flow bed; a gas outlet in the top of the multistage airflow shear cross flow bed is connected with a purified gas section; the absorption liquid is introduced to a liquid inlet in the side top of the multistage airflow shear cross flow bed; a liquid outletin the bottom of the multistage airflow shear cross flow bed is used for draining the absorption liquid; the liquid inlet is connected with a pump; the liquid outlet of the multistage airflow shear cross flow bed is connected with a liquid-rich tank; the multistage airflow shear cross flow bed comprises a liquid distributor, a liquid collecting and redistributing device, a rotor, a stator, a driving device and a casing. According to the equipment, the gas and the absorption liquid generally make counterflow contact, so that a gas-liquid mass transfer propulsion force is greater, the purification degree of the cracking gas is improved, and the concentration of methanol in the rich solution and the utilization rate of the absorption liquid are improved.
Owner:ZHONGBEI UNIV

Oxidation and blowout technological process and apparatus for bittern bromine process

The invention pertains to the technical field of extraction of bromine from brine, more particularly relates to the technique of oxidation and blow-out during the process of extraction of bromine from brine, and a device thereof, which improve the oxidation rate and blow-out rate of bromine during the extraction process and reduce energy consumption. The method is as follows: acid brine and chlorine are introduced into a rotating packed bed I, and the formed oxidation solution and air enter a rotating packed bed II to blow out free bromine. The device comprises two rotating packed beds, the liquid inlet of the rotating packed bed I is connected with a pump and the gas inlet thereof is connected with a chlorine pipe; the rotating packed bed I and the rotating packed bed II are connected by a storage tank; and the gas inlet of the rotating packed bed II is connected with a fan. The method has the advantages of improving the oxidation rate of bromonium ions, the utilization ratio of chlorine and the blow-out rate of free bromine, and reducing chlorine adding ratio, chlorine consumption amount, the causticity of the device during the process after the extraction of bromine and the process of salt extraction, gas-liquid ratio and operation cost; and the device occupies less land and is easy to be start and shut off and maintained.
Owner:ZHONGBEI UNIV

Device and method for removing sulfur dioxide in waste gas

The invention belongs to the field of waste gas desulfurization, and particularly relates to a device and a method for removing sulfur dioxide contained in a waste gas. The device and the method can be used for solving the problems of the traditional waste gas desulfurization technology. The device for removing the sulfur dioxide contained in the waste gas comprises an inverse shearing rotation packed bed, a barren solution storage tank, a pregnant solution storage tank, a barren solution circulation pump and a pregnant solution circulation pump, wherein an inverse rotation packed bed absorber is in a parallel flow structure; a gas and a liquid which are positioned in the inverse shearing rotation packed bed contact in a parallel flow way. The method for removing the sulfur dioxide contained in the waste gas comprises the following step: fast transferring SO2 contained in the waste gas to a desulfurization absorbing agent by carrying out multistage parallel flow contact on the desulfurization absorbing agent and the SO2-containing waste gas through multilayer inverse rotation packings and body resistance parts. The device disclosed by the invention has the advantages of small size, width treatment tolerance range, simple structure and easiness for operation. Compared with the traditional tower, the process disclosed by the invention has the advantages of high desulfurization rate, less gas-phase pressure drop, low energy consumption, low investment and operation cost, stability in operation, convenience for start and stop, and the like.
Owner:JIANGSU ZEYU ENVIRONMENTAL ENG

System device and process suitable for dehydrating liquefied natural gas on marine platform

The invention discloses a system device and a process suitable for dehydrating liquefied natural gas on a marine platform. The system device comprises a filtering separator, a first high-gravity machine, a triethylene glycol condenser, a poor/rich liquid heat exchanger, a booster pump, a buffering tank, a reboiler, a second high-gravity machine, a flash tank, a conveying pump, a first cutoff valve, a second cutoff valve, a third cutoff valve, a steam stripping agent condenser, a three-phase separator, a steam stripping agent dryer, a steam stripping agent storage tank, a steam stripping agentpump, a first flow meter, a second flow meter and a three-way valve. By adopting the system device, a high-gravity reactor is adopted for dehydration of natural gas and regeneration of triethylene glycol, so that the height and size of equipment can be reduced; the purity of regenerated triethylene glycol poor liquid can be increased to 99.999 percent by weight; when the triethylene glycol poor liquid is taken as an absorbent, the dew point of water at an outlet of natural gas subjected to water absorption treatment in an absorbing system can be lowered to -100 DEG C or less; and treatment requirement of the liquefied natural gas on space-limited occasions such as marine platform can be met.
Owner:BEIJING UNIV OF CHEM TECH
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