The invention discloses a black matte polyimide film. Carbon quantum dots, titanium dioxide powder, diamond powder and carbon black are uniformly distributed in the polyimide film. The preparation method of the black matte polyimide film comprises the following steps: adding carbon quantum dots, titanium dioxide powder, diamond powder and carbon black into an organic solvent, adding a dispersing agent, grinding to obtain black slurry; adding diamine and aromatic dianhydride into the black slurry, stirring, stopping stirring after the viscosity of the reaction system reaches 1500-4000 Pa.s, carrying out a vacuum defoaming treatment, forming a film, and heating to carry out imidization to obtain the black matte polyimide film. The black polyimide film has light transmittance of less than orequal to 0.45%, glossiness of less than or equal to 25GU, electric field breakdown strength of more than or equal to 140kV / mm, tensile strength of more than or equal to 210MPa and elongation at breakof more than or equal to 60.5% in a visible light range, and has a good shading effect, electrical insulation property and mechanical property.