The invention discloses graphene coating for corrosion prevention of a thermal power plant desulfurization chimney. The graphene coating consists of the following raw materials in parts by weight: 90 to 100 parts of film-forming resin, 0.5 to 3 parts of graphene, 0.5 to 2 parts of reinforced fibers, 10 to 20 parts of fillers, 10 to 20 parts of a curing agent, 15 to 30 parts of a diluents, 1 to 5 parts of polyacrylic acid, 1 to 5 parts of a polyethylenimin crosslinking agent, 1 to 3 parts of stearate and 2 to 6 parts of aids. By the mode of adding the raw materials, such as the reinforced fibers, the fillers, the polyethylenimin crosslinking agent and the polyacrylic acid, the defect that the existing corrosion-resistant coating has low durability and heat stability is overcome, the problem that the corrosion-resistant coating layer is easy to pollute and difficult to clean is solved, the developed graphene corrosion-resistant coating can completely adapt to the high-temperature strong-acid environment, the manufacturing process is simple, the practicability is high and the graphene coating is particularly suitable for thermal power plant desulfurization chimneys and flues.