75results about How to "Improve sintering properties" patented technology

The invention discloses a foaming thermoplastic polyurethane bead. The foaming bead comprises 100 parts of thermoplastic polyurethane particles, 1-10 parts of cell size stabilizer, and 1-35 parts of melt viscosity modifier. The bead is prepared through the following steps: steeping the thermoplastic polyurethane particles containing a cell size stabilizer and a melt viscosity modifier in an aqueous suspension and foaming by volatilizing foaming agent. The melt viscosity of the foaming thermoplastic polyurethane bead is 8000-15000 poise below 180 DEG C, the size of the prepared foaming thermoplastic polyurethane bead is stable, the diameter of the cell is uniform, the surface is bright, the yield of the product is high, the foaming thermoplastic polyurethane bead has good sintering property even under lower vapor pressure, and the molding foam product deforms slightly and has low shrinking percentage compared with the size of the die, good dimensional stability and attractive appearance.

The invention belongs to the technical field of preparation and application of electronic ceramics, and particularly relates to a method for finely synthesizing ternary ZnO-Nb2O5-TiO2 microwave dielectric ceramics by a wet chemical process. The technical scheme is as follows: the method comprises the following steps: 1) preparing a Zn ion citric acid water solution; 2) preparing a Ti and Nb ion citric acid water solution; and 3) synthesizing a ternary ZnO-Nb2O5-TiO2 microwave dielectric ceramic precursor, and preparing the ceramics. The invention has the advantages of low synthesis temperature, uniform ceramic particles, favorable dispersity, pure phase, nano particle size of powder, high specific surface energy, high activity and the like, can implement low-temperature sintering, and maintains favorable microwave dielectric properties, thereby satisfying the application requirements for LTCC (low temperature co-fired ceramic).

The invention discloses a method for preparing magnesium niobate microwave ceramic powder on the basis of sol-gel technique. The method comprises the following steps: (1) preparing the citric acid solution of niobium (Nb); (2) preparing the citric acid solution of magnesium (Mg); and (3) obtaining a Mg-Nb precursor solution, xerogel and nano-powder. The invention can overcome the disadvantages of high temperature and large particle size in the existing synthesis of magnesium niobate microwave ceramic powder on the basis of solid-phase method by preparing the magnesium niobate microwave ceramic powder with the average particle diameter being 40nm to 80nm under the condition that the calcination temperature is 550 to 850 DEG C.

The invention belongs to the technical field of electronic ceramic preparation and application, and particularly relates to a method for fine synthesis of a ternary MgO-Nb2O5-TiO2 system microwave dielectric ceramic by using a sol-gel method. The technical scheme comprises adopting a sol-gel method to finely synthesize a ternary MgO-Nb2O5-TiO2 system microwave dielectric ceramic, and specifically comprises: 1) preparing a citric acid aqueous solution of Mg ions; 2) preparing a citric acid aqueous solution of Ti ions and Nb ions; and 3) synthesizing a ternary MgTiNb2O8 microwave dielectric ceramic nanometer precursor, and preparing the ceramic. The ternary MgO-Nb2O5-TiO2 system microwave dielectric ceramic has significant advantages of low synthesis temperature, uniform ceramic particles, good ceramic particle dispersity, pure phase, nano-scale powder (particle size of about 50 nm), high specific surface energy, high activity and the like. In addition, compared with the conventional solid-phase method, the method of the present invention has the following characteristics that: the sintering temperature can be significantly reduced by 100-200 DEG C so as to achieve low temperature sintering, maintain the good microwave dielectric property, and meet the LTCC application requirements.

The invention discloses a piezoelectric material for lead-free piezoelectric ceramic with potassium-sodium niobate and a preparing method, which strengthens the ferroelectric performance of potassium-sodium niobate ceramic and further improves the piezoelectric performance. The material of the invention comprises anhydrous potassium carbonate, natrium carbonicum calcinatum, niobium pentaoxide and dibismuth trioxide, the stoichiometric proportion of the lead-free piezoelectric ceramic is (K0.5 Na0.5) Nb3 + x weight percent Bi 2O3, wherein the x is more than or equal to 0 and less than or equal to 1, the piezoelectric material for lead-free piezoelectric ceramic with potassium-sodium niobate is obtained through mixture making, drying and burnishing, granulation, molding, sintering and after polarization by a silver electrode; therefore, the densification of the ceramic is improved, polarized drain current of the ceramic is reduced, and the polarization process is carried out more easily; moreover, the piezoelectric material adopts the material from a conventional process and industry, has the characteristics of good process stability and no pollution.

A preparation process of intermediate temperature solid oxide fuel cell composite cathode material and cell cathode, relates to a preparation method of solid oxide fuel cell composite cathode material and cell cathode. The invention solves the problems that it has already been unsuitable for the cathode materials for high temperature fuel cell to work at middle temperature now and also the problems of the high production cost of adding noble metal Pt or Pd into electrode materials and also the oxides of sliver doped oxide composite electrode are all with perovskite structures. The general formula of composition of cell composite cathode material is La2-XSrXNiO4-Ag. The preparations of cell cathode are: first, prepare La2-XSrXNiO4, then prepare La2-XSrXNiO4 and electrolyte cathode assemblies, then drop AgNO3 for sintering and will obtain intermediate temperature solid oxide fuel cell composite cathode. The La2-XSrXNiO4 of intermediate temperature solid oxide fuel cell composite cathode materials in the invention is the K2NiF4 type oxides and the cell composite cathode material has holey microstructure, thereby improving the diffusion effect of gas and bringing down the production cost remarkably.

The invention discloses a method for preparing the sol-gel of Ag(Nb, Ta)O3 (silver tanto-niobate) nano-powder on the basis of the presence of potassium carbonate as a co-solvent. The method comprises the following steps: (1) preparing the citric acid solution of niobium; (2) preparing the citric acid solution of tantalum; (3) preparing the citric acid solution of silver; and (4) preparing the silver tanto-niobate (Ag(Nb, Ta)O3) sol and obtaining the nano-powder. The invention overcomes the defects of the preparing process caused by the existing presence of highly corrosive hydrofluoric acid and the Ag(Nb, Ta)O3 (silver tanto-niobate) ceramic nano-powder with the average particle diameter being 20 to 50 nm can be prepared.

The invention provides a Li series microwave dielectric ceramic material as well as a preparation method and use thereof. The Li series microwave dielectric ceramic material is prepared from main materials of Li2CO3, SiO2 and MgO, and substituted material NiO. The Li series microwave dielectric ceramic material has the excellent features of low dielectric constant, high quality factor, high relative density and low densification temperature. The preparation method of the Li series microwave dielectric ceramic material improves the sintering features, the micromorphology and the electric performance of Li2MgSiO4 microwave dielectric ceramic at the low sintering temperature of 1120 to 1160 DEG C; under the condition of adding a small quantity of sintering auxiliary agents, the sintering temperature lower than 961 DEG C can be realized.

The present invention relates to a method for manufacturing a conductive metal thin film, including: preparing a conductive metal coating solution by adding carboxylic acid to a dispersion including a conductive metal particle having a core/shell structure; coating the conductive metal coating solution on a top portion of a substrate, heat-treating it, and removing an metal oxide layer of the surface of the conductive metal particle having the core/shell structure; and forming a thin film of the conductive metal particle from which the metal oxide layer is removed.

The invention relates to a method for preparing superhigh temperature carbonized hafnium ceramic nano-powder. Anhydrous saccharose is evenly dispersed in deionized water, a mixed template is added, stirring is carried out, an even and transparent precursor solution is obtained, and the solution is poured into a hydrothermal still; the hydrothermal still is placed in an electric heating air blowing drying box for reacting after being sealed, then the product is cooled to room temperature, and filtering, separation, washing and drying are carried out; finally, the product is mixed with hafnium powder, a vacuum carburizing reaction is carried out, and HfC nano particles are prepared. Compared with the prior art, the prepared carbonized hafnium ceramic nano-powder is good in crystallinity and dispersity and controllable in morphology.

An object of the present invention is to provide a composite soft magnetic sintered material that has high density, high mechanical strength and high relative magnetic permeability at high frequencies and, in order to achieve this object, the present invention provides a method of producing the composite soft magnetic sintered material, which comprises mixing a composite soft magnetic powder, that consists of iron powder, Fe—Si based soft magnetic iron alloy powder, Fe—Al based soft magnetic iron alloy powder, Fe—Si—Al based soft magnetic iron alloy powder, Fe—Cr based soft magnetic iron alloy powder or nickel-based soft magnetic alloy powder (hereinafter these powders are referred to as soft magnetic metal powder) of which particles arc coated with a ferrite layer which has a spinel structure, with 0.05 to 1.0% by weight of silicon dioxide powder having a mean powder particle size of 100 nm or less and sintering the mixed powder after compression molding, or processing two or more kinds of the composite soft magnetic powders, of which particles are coated with ferrite layer having a spinel structure of a different compositions, by compression molding and sintering.

The invention discloses a preparation method of zinc cobalt sodium silicate microwave dielectric ceramic nano powder. The method comprises the following steps: (1) firstly preparing a zinc nitrate solution and a cobalt nitrate solution and then mixing the two solutions, wherein the raw material components and molar percentage content are shown in the following formula: CoxZn2-xSiO4, and x is larger than 0 and less than or equal to 1; (2) preparing a tetraethyl orthosilicate solution; (3) dropwise adding the mixed solution in the step (1) to the tetraethyl orthosilicate solution, wherein the pH value is 2-4, adding deionized water and then magnetically stirring so as to obtain CoxZn2-xSiO4 sol; (4) drying the CoxZn2-xSiO4 sol to form jelly-shaped gel, and then drying the gel to form dried gel; and (5) thermally treating the dried gel at the temperature of 650-950 DEG C so as to obtain the CoxZn2-xSiO4 nano powder. The CoxZn2-xSiO4 nano powder prepared by using the method has an averageparticle size of 90nm and has the advantages of high purity, simple process, cheap raw material, high activity and good sintering property; and the sintering temperature of the nano power is lowered by 100-300 DEG C as compared with that of a solid phase method, and a material support is provided for preparation of high-property CoxZn2-xSiO4 microwave dielectric ceramic.

Method for producing a porous titanium material for example a support. Starting from a titanium powder this powder is sintered under vacuum conditions in an inert/reducing atmosphere. Titanium hydride is added as powder and decomposes during sintering. The hydride ions provide a very reducing atmosphere preventing any titanium oxide or carbide/nitride composition to be formed at elevated temperature.

The invention discloses a method for preparing wide-working-temperature-zone thermostabilization composite dielectric ceramic. The method comprises the following steps of: (1) according to the formula of x(Na0.5Bi0.5)TiO3-(1-X)BaTiO3, preparing bismuth nitrate solution and sodium acetate solution, wherein x is more than 0.01 and less than 0.5; preparing tetrabutyl titanate solution, and dropwise adding the bismuth nitrate solution and the sodium acetate solution into tetrabutyl titanate solution to obtain sodium bismuth titanate sol; (2) preparing barium titanate solution; (3) preparing (Na0.5Bi0.5)TiO3-BaTiO3 composite sol; (4) preparing xerogel; (5) preparing (Na0.5Bi0.5)TiO3-BaTiO3 composite nano powder; and (6) pelleting and performing compression moulding, sintering at the temperature of between 950 and 1,050 DEG C to obtain the composite dielectric ceramic. The nano powder prepared by a sol-gel method has a fine particle size, and the average grain diameter of the powder is 100nm; and the powder has high activity and sintering property, and the wide-working-temperature-zone thermostabilization composite dielectric ceramic with high dielectrical property can be prepared at low sintering temperature.

The invention discloses a wear-resistant domestic ceramic and a preparation method thereof. The wear-resistant domestic ceramic comprises a domestic ceramic body and a glaze layer, wherein the glaze layer is prepared from the following raw materials in parts by weight: 30-40 parts of zircon sand, 10-15 parts of baddeleyite, 5-10 parts of nepheline syenite, 3-6 parts of titanium carbide powder, 3-5parts of titanium dioxide, 4-6 parts of lutetium oxide, 2-4 parts of tungsten powder, 2-4 parts of polyvinyl alcohol with mass fraction being 5 wt%, 2-4 parts of glycerin, and 20-30 parts of water. According to the wear-resistant domestic ceramic disclosed by the invention, through synergistic cooperation of the components, the obtained wear-resistant domestic ceramic is flat and smooth in glazesurface and good in texture, and has excellent hardness, bending strength and wear resistance.

The invention provides a low temperature co-fired ceramic (LTCC)-based metamaterial harmonic oscillator and a manufacturing method thereof. The manufacturing method comprises the following steps of: preparing ceramic slurry from nano ceramic powder, and casting to prepare a green tape; manufacturing a metal microstructure on the green tape to form green ceramic chips through screen printing; superposing the green ceramic chips, putting the green ceramic chips into a mold after tape ranking to form a presintering whole; and performing hot-pressing and cooling the presintering whole to obtain the metamaterial harmonic oscillator. Because the nano-powder has high sintering property, the sintering temperature of the nano ceramic powder can be reduced in the process of preparing the metamaterial harmonic oscillator from the nano ceramic powder; and therefore, a sintering aid is not added into the nano ceramic powder or a small amount of sintering aids can be added into the nano ceramic powder so as to realize low-temperature co-firing, and the loss of the metamaterial harmonic oscillator is reduced; by the hot-pressing technology, the phenomena of layering and warping in the sintering process are avoided, and the sintering temperature is lower than the traditional pressureless sintering temperature under the pressure conditions, and the sintering temperature is reduced further.

The invention belongs to the technical field of ceramic materials, and discloses a high-Q-value lithium titanate-based microwave dielectric ceramic material and a preparation method thereof. The preparation method comprises the following steps: subjecting Li2CO3 and TiO2 to burdening, ball milling, drying and sieving according to a stoichiometric formula Li2TiO3 and then performing presintering at a temperature of 800-1000 DEG C; adding an M doping agent, carrying out ball milling, drying, sieving and granulating successively, and conducting pressing to obtain a green body; and sintering the green body at a temperature of 1100-1180 DEG C. The chemical formula of the obtained high-Q-value lithium titanate-based microwave dielectric ceramic material is Li<2>TiO<3+x>M, wherein M is Li2CO3, MgO, LiF, MgF2 or MgO + LiF, and x is equal to 0.6 wt.%-3.6 wt.%. According to the invention, different types of dopants are introduced into Li2TiO3, so the sintering characteristic of microwave dielectric ceramic is improved, and the defect that the Qf value of pure Li2TiO3is low is overcome; the produced material has a high quality factor and a moderate dielectric constant; a preparation process is simple; and microwave dielectric devices manufactured, researched and developed on the basis of the material have wide application prospects.

The invention provides a preparing method of a superfine/nano tantalum tungsten composite powder. Adopting a fluorotantalic acid solution and tungstate as raw materials, the preparing method of the superfine/nano tantalum tungsten composite powder comprises the steps of firstly adding calculated amount of tungstate powder into the fluorotantalic acid solution, and then adding a surface active agent to prepare a sol solution; then adding an alkaline precipitant until pH is equal to 9 to 12, and precipitating to obtain a tantalum tungsten precursor composite powder; then carrying out hydrogen reduction, alkali metal reduction and magnesium reduction and deoxygenization to obtain the superfine/nano tantalum tungsten composite powder. The invention furthermore provides the superfine/nano tantalum tungsten composite powder prepared through the preparing method, wherein the grain size ranges from 10nm to 200nm, and the mass percent of tungsten ranges from 2.5 percent to 70 percent. According to the superfine/nano tantalum tungsten composite powder provided by the invention, the tantalum and tungsten components are distributed uniformly, and the sintering activity is high.

The invention discloses high-conductivity glass powder and a preparation method thereof, and a barium titanate-based glass ceramic based the high-conductivity glass powder, and a preparation method thereof. According to the present invention, 0.85BaTiO3-0.15Bi(Mg2/3Nb1/3)O3(BTBMN) ceramic powder is prepared by using a solid phase method, a low-melting-point high-conductivity glass B2O3-Na2B4O7-Na2SiO3(BNN) is prepared at a temperature of 900-1000 DEG C by using a melting method, high temperature taking and quenching is performed to obtain a glass, and a BTBMN-xBNN(BG)glass ceramic is preparedby using a solid phase method, wherein x represents the mass fraction of the BNN glass, and x is more than or equal to 1% and is less than or equal to 12%; the dense BG glass ceramic is obtained by sintering at a temperature of 850-1225 DEG C by adjusting the glass addition amount; the glass ceramic has an electric field strength of 240 kV/cm, a release energy density of 1.26 J/cm<3> and an energystorage efficiency of 81%, can meet a temperature change rate |[delta]C/C25 DEG C| of less than or equal to 15% within a temperature range of -61-275 DEG C, has good dielectric constant temperature stability, and can meet the temperature stability requirements of general capacitor operation; the glass ceramic material preparation process is simple, the technology is mature, and the method is suitable for industrial production; and the obtained glass ceramic has high puncture strength and good temperature stability.

The application discloses a Mn-doped ZrTi2O8/ZnNb2O8 composite microwave dielectric ceramic and a preparation method thereof, wherein the mass proportion of ZrTi2O8 is 65wt%, the mass proportion of Mn is 1.2wt%, and the balance is ZnNb2O8. The preparation method of Mn-doped ZrTi2O8/ZnNb2O8 composite microwave dielectric ceramics includes: 1. Synthesizing ZrTi2O8/ZnNb2O8 base material by solid phase method; 2. Adding MnCO3 to ZrTi2O8/ZnNb2O8 base material; 3. Adding MnCO3 base material Put it into a polyurethane ball mill tank for ball milling; 4. Dry and sieve; 5. Granulate; 6. Dry press molding; Keep warm at 1250°C for 5 hours; 8. Cool to room temperature. The invention effectively improves the sintering characteristics of the dielectric ceramics through Mn doping modification, can be sintered densely in the air at 1250 DEG C, and has good microwave dielectric properties.

The invention provides a tin oxide target material doped with silver as well as a preparation method and application thereof and belongs to the technical field of preparation of target material. The tin oxide target material is prepared from Ag powder and SnO2 powder, wherein the mass ratio of Ag powder to SnO2 powder is (1:50)-(1:100). Ag is doped in the tin oxide target material to improve the sintering performance of SnO2 based target material and increase the density of the target material, and the density of the target material affects the sputtering rate, and the electrical and optical property of a film. The higher the density of the target material is, the higher the performance of the film is, and the film can better bear the thermal stress during the sputtering process. In addition, the resistance to oxidation of the target material can be improved to prolong the service life of the film.