The invention discloses a coating material for electrostatic spraying on a polypropylene automobile bumper bar. The coating material is prepared from 8-15 parts by weight of polyurethane resin ester, 10-20 parts by weight of polyester resin, 18-28 parts by weight of modified functional resin, 5-10 parts by weight of ethyl acetate, 5-10 parts by weight of butyl acetate, 0.5-2 parts by weight of an auxiliary agent, 5-10 parts by weight of acrylic resin, 0.5-2 parts by weight of a resistance regulator and 30-40 parts by weight of colorant paste. The preparation method comprises the following steps: a. adding the polyurethane resin ester, the polyester resin, the modified functional resin, the ethyl acetate, the butyl acetate, the auxiliary agent, the acrylic resin and the resistance adjusting agent into a blending kettle and carrying out uniform stirring, b. according to the color of the automobile coating, adding 80-95% of the corresponding colorant paste into the above mixture, carrying out stirring, detecting the color of the coating film, and according to color difference, continuously adding different colorant paste to adjust the color so that the coating film color satisfies the standard, and c. carrying out detection, and when the coating film is qualified, carrying out filtration and packaging.