The invention discloses super-weatherability anti-acid rain raindrop imprint-resistant external wall water paint and a preparation method thereof. The super-weatherability anti-acid rain raindrop imprint-resistant external wall water paint comprises deionized water, a thickener A, a wetting agent A, a wetting agent B, a dispersant, a defoamer, a film forming aid, a pH stabilizer, an antifreezing agent, titanium dioxide, barite, mica powder, calcined kaolin, a modified polymer emulsion, a thickener B, a leveling agent, a bactericidal mildew preventive and deionized water according to mass percents. The super-weatherability anti-acid rain raindrop imprint-resistant external wall water paint has acid and alkali resistance, weatherability, water resistance, mildew proof effects, raindrop imprint resistance, scrubbing resistance, environmental friendliness and energy saving.