The invention provides a
cerium-
zirconium co-doped porous structure positive
electrode material and a preparation method thereof. The method comprises the following steps: (1) preparing a ternary solution, a
cerium-
zirconium blended
salt solution, a precipitant solution and a complexing agent solution for later use; (2) preparing a base solution and stirring; (3) injecting the ternary solution, the
mixed solution of the
cerium salt and the
zirconium salt, the precipitant solution and the complexing agent solution into the base solution, carrying out reaction of the stage I and the
stage II, and stopping feeding until the reaction reaches the target particle size; (4) centrifugally washing,
drying, screening and deironing the reacted
slurry to obtain a precursor; and (5) mixing the precursor with a
lithium source, and
sintering to obtain the positive
electrode material. According to the preparation method, the blended cerium-zirconium
salt solution is doped into the ternary solution byutilizing liquid-phase
doping, so that doped elements are uniformly distributed, and the battery cycle performance of the material is improved by utilizing the synergistic effect of the doped elements; the positive
electrode material with a pore structure, high purity and good performance is prepared through
process control in different reaction stages.