The invention discloses a prestressed ceramic and a preparation method thereof, comprising a green body and a first prestressed layer on the surface of the green body, the thermal expansion coefficient of the first prestressed layer is smaller than that of the green body; the raw material of the first prestressed layer Including calcite, kaolin, quartz, spodumene, zinc oxide, barium carbonate and frit; wherein, the raw materials of frit include kaolin, quartz, talc, dolomite, alumina, zinc oxide, wollastonite and spodumene. In the prestressed ceramics of the present invention, the first prestressed layer is respectively arranged on the surface and the bottom surface of the green body, and when the ceramic is subjected to a certain external tensile stress, it will be offset by the prestressed force of the first prestressed layer, thereby greatly improving The strength and toughness of the ceramics prevent the ceramic structure from being destroyed, and solve the problems of low impact resistance and low strength of the existing ceramics. Preferably, the prestressed ceramics of the present invention belong to the field of architectural ceramics.