The invention belongs to the field of high molecules, and particularly relates to thermal plastic processing available polyvinyl alcohol resin, as well as a preparation method and application thereof. To solve the technical problems, the method comprises the following steps: based on mass percentage, adding 15-45 parts of imidazole ionic liquid into water, sufficiently dissolving and ionizing; then, adding 100 parts of polyvinyl alcohol, uniformly mixing to obtain a mixture, and standing at 65-90 DEG C for plasticizing; and removing moisture. The thermal plastic processing available polyvinyl alcohol resin can be applied to the fields of thermal plastic processing, such as extrusion, injection molding, membrane blowing, spinning, foaming and fused deposition modeling. The preparation method is simple and efficient, has strong operability, and is easy for industrial implementation. Products prepared by adopting the polyvinyl alcohol resin as a raw material has excellent mechanical performance and excellent conductive performance.