10 results about "Iron cyanide" patented technology

The present application discloses a method for treating and resourcefully recycling electroplating cyanide copper wastewater, belonging to the technical field of electroplating wastewater treatment. In this application, the cyanide copper wastewater is adjusted with strong base, and a ferrous sulfate solution is added to the cyanide copper wastewater after strong base adjustment for a combination reaction; the cyanide copper wastewater after the combination reaction is adjusted with acid and subjected to a Prussian blue reaction; a coagulant aid is added to the solution after the Prussian blue reaction, and solid-liquid filtration separation is carried out on it to obtain iron cyanide sludge and preliminarily precipitated cyanide-removing wastewater; the preliminarily precipitated cyanide-removing wastewater is adjusted with weak base, hydrogen peroxide is added to the preliminarily precipitated cyanide-removing wastewater after weak base adjustment, and the copper in the preliminarily precipitated cyanide-removing wastewater after weak base adjustment is used as a catalyst for an oxidation reaction to remove the remaining cyanide-containing pollutants; after the oxidation reaction is completed, lime is added for flocculation precipitation to obtain copper sludge, thus realizing a one-step process flow, converting copper cyanide compounds into resources that can be recycled, and improving the resource utilization rate.

The invention provides a process for removing cyanide from a cyanide-bearing aqueous fluid, the process comprising: (i) adding a solid composition comprising a first mixed-metal cyanide complex comprising copper and iron to a cyanide-bearing aqueous fluid comprising free cyanide and metal-complexed cyanide, wherein at least a portion of the first mixed-metal cyanide complex dissolves, with complexation of the copper by the free cyanide, to produce an aqueous solution comprising cyanometallates, the cyanometallates comprising copper cyanide and iron cyanide complexes derived from the first mixed-metal cyanide complex; (ii) contacting the aqueous solution with an anion-exchange absorbent to absorb the cyanometallates, thereby producing a cyanide-lean aqueous fluid; (iii) extracting the anion-exchange absorbent comprising the absorbed cyanometallates with at least one non-acidic aqueous extractant to produce an aqueous extract comprising the copper cyanide and iron cyanide complexes; and (iv) acidifying the aqueous extract to produce a precipitate comprising a second mixed-metal cyanide complex comprising copper and iron.

The invention belongs to the technical field of medicine synthesis, and discloses a preparation method of a sodium nitroprusside raw material medicine. According to the method, weak acid is adopted for catalysis, the effect of remarkably reducing generation of toxic substances such as cyanide and nitrogen dioxide is achieved by controlling the material dripping speed and the dripping pH, the reaction is mild, the technological operation is safe and controllable, and industrial production of the sodium nitroprusside raw material medicine is facilitated. According to the preparation method of some examples, silica gel filtration is used for post-treatment, the residual risk of impurities such as sodium ferricyanide, ferric ferrocyanide and ferric ferricyanide is reduced, and the purity of the raw material medicine is larger than or equal to 99.9% and is far superior to the requirements of pharmacopoeia of various countries.

The application belongs to the field of fuel cells, and particularly relates to a preparation method of a single-iron atom catalyst. A solution containing component A, component B and component C is subjected to a coprecipitation reaction to obtain a precipitate; the precipitate is aged in a component D solution to obtain an aged product; and the aged product is subjected to gradient calcination to obtain the single-iron atom catalyst. The component A contains a compound of formula 1; the component B contains at least one of iron cyanide, dopamine and a salt thereof; the component C contains an iron source and a zinc source; and the component D contains a water-soluble compound having a fragment of formula 3. The application also discloses a material prepared by the method and an application of the material in ORR and fuel cells. Research shows that the material prepared by the method has excellent catalytic activity and stability in ORR, and a metal-air battery assembled by using the material can have excellent limiting current density, peak power and discharge specific capacity.

This application provides a method for the electrocatalytic oxidation removal of medium-to-high concentration iron cyanide complexes, belonging to the field of ferric cyanide wastewater treatment. This application involves adding a chlorine-containing electrolysis promoter to wastewater containing medium-to-high concentrations of iron cyanide complexes to obtain a solution to be electrolyzed; using a platinum-titanium electrode or a ruthenium-iridium-titanium electrode as the anode and a foamed copper electrode as the cathode, the solution to be electrolyzed is subjected to electrocatalytic oxidation treatment; during the electrocatalytic oxidation process, a pH adjuster is used to maintain the pH of the liquid phase >10; after the electrocatalytic oxidation treatment is completed, solid-liquid separation is performed to obtain filter residue and filtrate. By selecting specific types of anodes and cathodes and adding a chlorine-containing electrolysis promoter, this application can promote the decomposition and transformation of iron cyanide complexes, ultimately converting cyanide into carbonate ions and nitrogen gas, achieving efficient removal of medium-to-high concentrations of iron cyanide complexes safely and environmentally.

The invention discloses an auxiliary electrolyte-free high-specific-capacity and stable-circulation flow battery positive electrode electrolyte as well as a preparation method and application thereof, and relates to the field of flow batteries. The positive electrolyte is composed of iron cyanide with the molar concentration of 0.1-3 mol / L and the balance of water, the iron cyanide contains complex cations, and the complex cations are at least two of Li < + >, Na < + >, K < + > and NH4 < + >. No auxiliary electrolyte is added into the positive electrode electrolyte, the cyanide solubility of iron can be effectively improved through the hetero-ion effect, when the positive electrode electrolyte is subsequently applied to assembly of the iron-based flow battery, the specific capacity and the cycling stability of the flow battery are improved, and moreover, the electrolyte is neutral and has low requirements on acid and alkali corrosion resistance of corollary equipment, so that the positive electrode electrolyte can be applied to the assembly of the iron-based flow battery. The applied iron-based flow battery has low cost and practicability in an energy storage technology, and is beneficial to a large-scale commercialization process.

This invention belongs to the field of pharmaceutical synthesis technology and discloses a method for preparing sodium nitroprusside raw material. The method employs weak acid catalysis and significantly reduces the generation of toxic substances such as cyanide and nitrogen dioxide by controlling the material dropping rate and pH. The reaction is mild, the process is safe and controllable, and it facilitates the industrial production of sodium nitroprusside raw material. In some examples of the preparation method, silica gel filtration is used in the post-processing to reduce the residual risk of impurities such as sodium ferrocyanide, ferrous ferrocyanide, and ferric ferric ferrocyanide. The purity of the raw material is ≥99.9%, far exceeding the requirements of pharmacopoeias of various countries.

This invention discloses a method for suppressing water migration in a zinc-iron flow battery by adjusting the volume ratio of the positive and negative electrolytes, belonging to the field of flow battery technology. The positive electrolyte of the zinc-iron flow battery is an alkaline solution of iron cyanide complex ions, and the negative electrolyte is an alkaline solution of zincate ions. The volume ratio of the positive to negative electrolyte is 0.5-5:1; preferably 1-4:1; more preferably 2-4:1. The alkalinity of both the positive and negative electrolytes is 0.05-5 mol / L. This invention can effectively suppress water migration during the operation of the zinc-iron flow battery, improve its lifespan, and reduce maintenance costs during battery operation.

The invention discloses a red mud-based PBAs-derived metal oxide Fenton catalyst and a preparation method and application thereof, belonging to the technical field of iron-based Fenton catalysts. Red mud is added to deionized water, and hydrochloric acid is added after dispersion; after sufficient reaction, a transition metal salt is added, and potassium ferrocyanide solution is added dropwise after stirring and dissolving; after stirring and sufficient reaction, solid-liquid separation and washing are performed, and the obtained solid material is roasted to obtain a catalyst. Under the conditions of a catalyst concentration of 0.05-2g / L, a H2O2 concentration higher than 0.5mM, a pollutant concentration of 50ppm, an initial pH of 3-11 and a temperature of 30°C, more than 90% of the reactive black 5 dye (RB5) can be degraded within 5-30min. The method of the invention can develop an efficient red mud-based catalyst, improve the utilization rate of red mud, achieve efficient purification of organic wastewater, and achieve waste treatment with waste.