The invention discloses a high-foam-stability concrete air entraining agent with a multi-
substructure and a preparation method of the high-foam-stability concrete air entraining agent. The air entraining agent comprises a
polyamine main chain, a hydrophobic chain mounted on the
polyamine main chain and a
phosphonate anion functional group grafted on the
polyamine main chain. The molecular structure of the air entraining agent provided by the invention has the advantages of multi-type,
high surface activity, lower
solid doping amount compared with the conventional air entraining agent, uniform and fine bubbles can be generated when the air entraining agent is added into premixed concrete, the stability of the bubbles in time is excellent, the workability of the premixed concrete can be greatly improved, and the bleeding rate and the
slurry bleeding rate are obviously reduced; the branched chains are multi-sub-chains, good air entraining and foam stabilizing effects are achieved, the main chain has a good reinforcing effect, concrete
strength reduction caused by increase of the
air content is made up, and the air entraining and foam stabilizing performance of the whole
system is kept excellent; phosphonic acid groups in molecules of the air entraining agent are insensitive to components of concrete and mineral admixtures and have relatively weak adsorption capacity to clay, so that the air entraining agent has relatively good retarding and
slump retaining properties.