The invention aims to provide a novel high-temperature-resistant and anti-corrosion ceramic coating which can resist strong-acid corrosion at the high temperature, has good wear-resisting property and heat conductivity, low spraying cost and long service life and can be firmly attached to walls of related equipment, and a preparation technology. The novel high-temperature-resistant and anti-corrosion ceramic coating comprises, in parts by weight, 45-50 parts of nano ceramic powder, 10-15 parts of powdery quartz, 10-15 parts of polyurethane resin, 5-8 parts of dodecylene alcohol ester, 3-4.5 parts of powdery calcium carbonate, 3-5 parts of cobalt powder, 2-3 parts of powdery purple clay, 1-2 parts of powdery silicon dioxide, 0.5-1 part of paraffin, 5-8 parts of ethyl acetate, 5-8 parts of n-butyl alcohol and 1-5 parts of powdery vermiculite.