The invention discloses a wire rod for a CO2 gas shielded welding wire with tensile strength of 650MPa for a coating-free weathering steel bridge, and belongs to the field of weathering steel weldingmaterials. The wire rod comprises the following chemical components in percentage by mass: 0.04 to 0.09 percent of C, 0.55 to 0.85 percent of Si, 1.70 to 2.10 percent of Mn, less than or equal to 0.015 percent of P, less than or equal to 0.005 percent of S, 0.46 to 0.65 percent of Cr, 1.10 to 1.80 percent of Ni, 0.15 to 0.38 percent of Cu, 0.10 to 0.20 percent of Ti, 0.003 to 0.005 percent of B, less than or equal to 0.015 percent of Al, less than or equal to 0.045 percent of Zr, less than or equal to 0.030 percent of Ce, less than or equal to 0.050 percent of O, less than or equal to 0.070 percent of N, and the balance of Fe and inevitable impurities. The invention also discloses the CO2 gas shielded welding wire with the tensile strength of 650MPa for the coating-free weathering steel bridge, which is prepared by drawing the wire rod. The welding wire is used for welding coating-free weathering steel with the tensile strength of 650MPa, wherein the tensile strength of deposited metalis between 650MPa and 730MPa, and the welding wire has high crack resistance; and the yield strength is more than or equal to 500MPa, the elongation is more than or equal to 23 percent, and the low-temperature impact energy KV2 at the temperature of -40 DEG C is more than or equal to 60J.