The invention relates to a steam-curing free coal ash brick and a making method thereof. According to the steam-curing free coal ash brick and the making method thereof, coal ash, cement, gypsum, aggregate, an alkali mixing material, an excitant, a water retaining agent, a fiber and water are adopted as raw materials, and a coal ash brick which meets strength standard requirements is made throughpremixing, aging, cloth pressing and steam-curing free normal-temperature maintenance. By adopting the steam-curing free coal ash brick and the making method thereof, efficient utilization of coal ashis achieved, the mixing utilization rate is greater than 70%, reactions can be implemented at a normal temperature, steam-curing is avoided in a maintenance mode, energy-saving production is achieved, coal ash bricks which meet strength standard requirements can be made, and remarkable environment benefits, economic benefits and social benefits can be made.