The invention discloses a preparation method and an application for a metal ion neutral-meson morpholine molecularly imprinted polymer. The method comprises the following steps of: (1) adding morpholine, 4-vinyl pyridine, metal cobalt (II) ions, dimethyl sulfoxide and acetonitrile in a container, ultrasonically preparing prepolymerization solution, standing, then adding EDMA (ethylene glycol dimethacrylate) and AIBN (2,2-azobisisobutyronitrile), charging argon, uniformly mixing, sealing, and reacting for 24 hours in a 60 DEG C water bath; and (2) after polymerization is finished, grinding, sieving, settling by using methyl alcohol and acetone, then eluting template molecule morpholine by using a solvent, and drying in vacuum. The morpholine molecularly imprinted polymer obtained by the method disclosed by the invention has high selective absorption capacity to the morpholine molecules, can be used for solid-phase extraction of morpholine, and is applicable to the needs of some special occasions.