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Superficial layer geological displacement monitoring and early-warning system and method

The invention relates to a geological exploration technology, in particular to a superficial layer geological displacement monitoring and early-warning system and a superficial layer geological displacement monitoring and an early-warning method. The system comprises a sensor module, a communication module, an information processing module and an early-warning module. When a geological accident occurs at the monitoring points, the angle sensor module can monitor the offset, the communication module transmits the monitored offset to the information processing module, the information processing module converts the offset into offset displacement, calculates the offset center and the average offset value of the monitoring point according to the offset displacement, judges whether the average offset value meets the early-warning condition or not and transmits triggering information to the early-warning module if the average offset value meets the early-warning condition, and the early-warning module sends out an early-warning signal according to the received triggering information. The monitoring and early-warning system and the monitoring and early-warning method are high in monitoring accuracy and realize all-weather and dynamic monitoring. The monitoring system is low in mounting, using and later maintenance costs. The monitoring and early-warning method is easy to operate and control and suitable for popularization.
Owner:CHONGQING UNIV

Dinuclear nickel coordination compound and preparation method and application thereof

The invention discloses a dinuclear nickel coordination compound and a preparation method and an application thereof. The coordination compound is [(dmbpy)2Ni2Cl4(H2O)2] and has molecular structure ofC24H28Cl4N4Ni2O2; wherein the dmbpy is 4,4'-dimethyl-2,2'-bipyridine and Ni is a bivalent nickel ion. The compound is in the form of solid crystal. The crystal of the coordination compound belongs totriclinic system and has P-1 space groups. The dinuclear molecular structure is formed with the 4,4'-dimethyl-2,2'-bipyridine and the nickel ion through a chlorine bridge bond. The preparation methodincludes: performing a reaction on nickel triphenylphosphine dichloride [NiCl2(PPh3)2] and the 4,4'-dimethyl-2,2'-bipyridine in an acetonitrile solution to obtain a green precipitate, dissolving theprecipitate in an acetonitrile / ethanol mixed solution for slowly volatilizing the liquid to obtain a green crystal. The product can be used as a photocatalyst in order to convert a greenhouse gas, CO2, into CH4 and CO having high additional value. The preparation method is easy to carry out and is high in product purity and yield. The coordination compound has excellent application prospect in thefield of photocatalytic conversion of CO2.
Owner:YUNNAN NORMAL UNIV

Green method for preparing amine derivatives from alcohols and amines

The invention discloses a green method for preparing amine derivatives from alcohols and amines. Different amine derivatives are prepared from alcohol and amine compounds by virtue of a controllable high-selectivity alkylation reaction under the catalysis of a nontransition metal catalyst and under the condition of no solvent; the nontransition metal catalyst is a halohydrocarbon and the dosage of the halohydrocarbon is 1-50mol%; a dehydration reaction can be directly performed on the alcohols and the amines under the catalysis of the halohydrocarbon to obtain the amine derivatives, and the reaction temperature ranges from 100 to 180 DEG C, the reaction time is 12-48 hours and the byproduct is water; the reaction needs to be performed under the protection of an inert gas, the conditions are simple and easy to operate, the byproduct is water, the reaction selectivity is controllable and the target selectivity is high. The requirements on the reaction conditions are reduced; the primary alcohol and the secondary alcohol can be used as alkylation reagents and suitable for the dehydration mono-alkylation reaction of the primary amine and the secondary amine and also for the dehydration dual-alkylation reaction of the primary amine; the green method for preparing the amine derivatives from the alcohols and the amines have a wide application range and ought to have certain research and industrial application prospect.
Owner:WENZHOU UNIVERSITY

Mononuclear nickel coordination compound, and preparation method and application thereof

The invention relates to the technical field of coordination compound materials, and discloses a mononuclear nickel coordination compound, and a preparation method and an application thereof. An organic ligand 1,2-bis(dicyclohexylphosphino)ethane and nickel ions form the mononuclear nickel coordination compound having a chemical formula of C26H48Cl2NiP2 through a chlorine bridge bond. The coordination compound is a solid crystal, and the crystal belongs to a triclinic system and a P1 space group. The preparation method comprises the following steps: reacting a bis(triphenylphosphine)nickel chloride solid with 1,2-bis(dicyclohexylphosphino)ethane in an acetonitrile solution to obtain a yellowish-brown precipitate, then dissolving the precipitate in a mixed solution of acetonitrile and ethanol, and slowly volatilizing the solvents to obtain the yellow-green crystal. The compound can be used as a photocatalyst to convert greenhouse gas carbon dioxide into methane gas with high added values and CO. The preparation method has the advantages of simplicity, easiness in implementation, and high purity and high yield of the product, and the product has a good application prospect in the field of photocatalytic conversion of carbon dioxide.
Owner:KUNMING INST OF BOTANY - CHINESE ACAD OF SCI
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