The invention discloses compound enzyme used for methane gas fermentation and capable of supplementing trace elements, which is used for quickly decomposing raw materials in methane gas fermentation to supplement the trace elements so as to quicken gas production and increase gas yield. The compound enzyme comprises an enzyme preparation part and a trace element part, wherein the enzyme preparation part is prepared by compounding the following solid monomeric enzyme raw materials in percentage by weight: 20 to 30 percent of 20,000u/g xylanase, 20 to 30 percent of 20,000u/g cellulose, 5 to 10 percent of 1,500u/g lipase, 5 to 10 percent of 10,000u/g pectinase, 5 to 10 percent of 30,000u/g saccharifying enzyme and 5 to 10 percent of 10,000u/g glucanase; the trace element part is prepared from the following raw materials in percentage by weight: 10 to 15 percent of zinc sulfate, 20 to 30 percent of powdered rock phosphate, 10 to 20 percent of steelmaking slag, 12 to 16 percent of calcium carbonate, 20 to 25 percent of stove ash, 5 to 10 percent of active carbon and 4 to 8 percent of nonionic surfactant; and a weight ratio of the enzyme preparation part to the trace element part is 1:(1-2). The compound enzyme can produce gas quickly, increase gas yield, prolong fermentation time, reduce residual energy and improve utilization rate of the raw materials.