This invention provides a PDA / ODT-ODTMS
composite coating and its preparation method, relating to the field of
metal surface protection technology. The
coating comprises, from the inside out, a polydopamine intermediate layer and a co-deposited functional layer of n-octadecyl mercaptan /
octadecyltrimethoxysilane. The preparation method involves first electrodepositing a PDA intermediate layer on the
substrate surface, then immersing it in an aqueous
micelle deposition solution composed of n-octadecyl mercaptan,
octadecyltrimethoxysilane, and a surfactant, and forming the composite functional layer through isothermal
chemical deposition. This invention, through molecular-level co-deposition of ODT and ODTMS combined with an aqueous
micelle process, constructs a firmly adhered, dense, and highly hydrophobic
protective barrier on the
metal surface, significantly improving the long-term
corrosion resistance and stability of the
coating, while also making the preparation process
safer and more
environmentally friendly.