256 results about "Multiple-effect evaporator" patented technology

In a composite process for subjecting ethylene to catalytic gas phase oxidation thereby obtaining ethylene oxide and causing this ethylene oxide to react with water thereby obtaining ethylene glycol, a method for producing the ethylene glycol is provided which permits effective utilization of the energy at the step for dehydrating and concentrating the resultant aqueous ethylene glycol solution. In the production of ethylene glycol by the supply of the aqueous ethylene glycol solution to a concentrating treatment at the multi-effect evaporator, the method contemplated by this invention for the production of ethylene glycol comprises utilizing as the source of heating at least one specific step the steam generated in the multi-effect evaporator.

The invention relates to an evaporative crystallization process, in particular to the multifunctional multi-effect automatic continuous evaporative crystallization process and a crystallization device. The process preheats unsaturated water solution or organic solution of materials and carries out the continuous evaporation to the material liquid by a multi-effect evaporator, the temperature of the multi-effect evaporator is gradually reduced and the vacuum degree is gradually increased; when the concentration of the material liquid achieves the saturation, the material liquid enters a crystallizer for the flash evaporation crystallization, and products after the crystallization are subjected to the solid-liquid separation in a centrifuge; the unsaturated solution after the centrifugalization is sent back to the device for the further evaporation crystallization, and the evaporated water or the organic solvent is recycled for use after cooling, thereby realizing the continuous production. The evaporative crystallization process can greatly reduce the labor use and improve the productivity, thereby directly bringing economic benefits to enterprises which use the device and simultaneously reducing the national energy consumption.

The invention relates to a recycled flue gas desulfurization and denitration method, which sequentially comprises the following steps of: introducing flue gas of SO2 and NOx into a desulfurizing tower, and absorbing the SO2 with a desulfurizing agent (barren liquor) in the desulfurizing tower; desorbing the desulfurizing agent (rich liquor) which absorbs the SO2 through a multi-effect evaporator,releasing the SO2 gas, and concentrating the SO2 gas into liquid SO2 through condensation drying; making the desulfurized flue gas enter a denitration tower, injecting gaseous ozone from an ozone generator, oxidizing the NO in the flue gas, absorbing the oxidized NO by using a denitrifier to form nitrate; crystallizing and separating out the nitrate in the solution after the nitrate reaches certain concentration, and filtering and drying to obtain the nitrate product. The method turns the wastes into wealth, and the SO2 and NOx in the flue gas are recycled by higher-additional value liquid SO2 and nitrate products, so that the recycling and value maximization in the desulfurization and denitration process is realized. Due to the adoption of the technical scheme, the high desulfurization and denitration rate can be achieved, the desulfurization rate is over 96 percent, the denitration rate is more than 90 percent, and the purity of the nitrate product is over 96 percent. The method hasthe advantages of simple desulfurization and denitration process, low investment, and low operation cost for desulfurization and denitration, and solves the problems that the conventional desulfurization and denitration process has high cost, generates a side product of a mixture of sulfuric acid (sulfate) and nitric acid (nitrate), and has low additional value.

The invention discloses a low-temperature multieffect seawater distillation desalting system. The system comprises a plurality of multi-effect evaporator sets; each evaporator set is at least provided with a heater for preheating feeding seawater; an effect intermediate pump is arranged between two adjacent multi-effect evaporators; and one end of a condenser is connected with a raw material water pump, and the other end of the condenser is connected with the last evaporator set of the plurality of the multi-effect evaporator sets. The invention also discloses a process flow for utilizing the low-temperature multieffect seawater distillation desalting system to desalt seawater; the evaporators of the low-temperature multi-effect seawater distillation desalting system are divided into a plurality of sets; each set feeds in parallel; simultaneously, the front of the feeding seawater of the highest-temperature effect evaporator of each set is provided with a heater; residual strong brine of the front evaporator set is collected and beaten to the next evaporator set through the effect intermediate pump, and so on; a product water and strong brine flow in a ladder shape in a series of flash tanks and are gradually subjected to flash evaporation and cooling; steam obtained through flash evaporation enters the evaporator; and finally, the product of the cooled water and the strong brine are pumped out through a corresponding water pump respectively.

The invention discloses a method for purifying smelting waste acid. The method comprises the following steps: adding a coordination agent into a centralized inflow adjusting pool of waste acid discharged from a sulfuric acid smelting system, stirring uniformly, and filtering the mixture in a filter to further remove insoluble granular impurities; separating dilute acid nearly containing no metal ion and low-acid wastewater through a diffusion dialyzer; adsorbing such residual anion impurities as fluorine and chlorine in the dilute acid through ion exchange resin, concentrating the dilute acid in a multi-effect evaporator and recycling the dilute acid in the sulfuric acid system; further treating the low-acid wastewater to reach the national sewage drainage standard. The method disclosed by the invention can be used for quickly and efficiently separating acid from heavy metal ions in the smelting waste acid, the separated dilute acid can be recycled in a sulfuric acid production procedure after being concentrated, and the method has the advantages of low energy consumption and few residues, and can be used for effectively and comprehensively recycling resources in the waste acid. The wastewater treatment cost is low, and the economic benefit is good. The process is simple, the occupation area of equipment is small and industrialized application is easy to achieve.

Embodiments provided herein include methods and apparatuses for purification and recycling of hydrofracture water used in natural gas drilling and production. Embodiments include removal of dissolved solids by precipitation with sodium sulfate and by evaporation using, for example, a multiple effect evaporator.

The invention discloses an energy-saving low-temperature multiple-effect seawater desalting device, which is used for solving the problems of high operation cost and unstable operation of a desalting device. The energy-saving low-temperature multiple-effect seawater desalting device comprises a steam ejector, evaporators and a condenser, wherein multiple effect evaporators are connected in series; after improvement, the heat source of the device consists of a steel mill off-gas pipeline and a waste heat boiler; the waste heat boiler converts steel mill waste heat off-gas into saturated steam and overheat steam; the saturated steam and overheat steam are introduced into the first effect evaporator through the steam ejector; and the outlet of the last effect evaporator is connected with the condenser. The energy-saving low-temperature multiple-effect seawater desalting device has the advantages that: a, the waste heat boiler is introduced, the steel mill off-gas is fully utilized, the energy is saved, the operating cost of the device is reduced, and the pollution of the steelmaking off-gas on the environment is reduced; and b, the heat of finished water and strong brine is fully utilized, the temperature of the seawater at the inlet and outlet of the condenser is kept stable through intelligent pipeline control despite of the change of the temperature of seawater, and the equipment has the stable and optimized running state.

The invention discloses a full-automatic descaling multi-effect evaporator, which comprises a heater and an evaporation chamber, wherein a granule distributor which can make fluid be distributed to tube nests of the heater uniformly is arranged at the bottom of the heater; and a granule separator is also arranged between the heater and the evaporation chamber. Due to the adoption of the technical scheme, the full-automatic descaling multi-effect evaporator has the advantages that a descaling process can be simplified, heat transfer is enhanced, and a heat transfer coefficient is increased, so that the evaporator can clean and remove scales online to realize continuous production. According to the optimized technical scheme, an intensifier ring is arranged in the granule separator, and a granule separation chamber and a granule storage chamber are also formed in the granule separator, so that liquid forms a vortex which rotates at high speed when passing through the cylindrical granule separation chamber under the action of centrifugal force formed by the intensifier ring to do circular rotary motion, so that granular solids are separated from the liquid quickly.

The invention provides a comprehensive utilization method of thermal power plant boiler wastewater. The comprehensive utilization method comprises the following process steps: (1) continuous boiler wastewater goes into a continuous blowdown flash tank for reduced-pressure flashing; secondary steam generated after flashing is guided out of the upper part of the continuous blowdown flash tank and into a deaerator; (2) the hot wastewater at the bottom of the continuous blowdown flash tank is guided into a boiler periodic blowdown flash tank for further reduced-pressure flashing together with regular boiler wastewater; (3) the secondary steam generated by flashing from the periodic blowdown flash tank serves as a heat source and is guided into a low-temperature multiple-effect evaporator group, and bottom salt-containing wastewater also goes into the low-temperature multiple-effect evaporator group as the evaporated liquid; (4) the condensed water generated by the low-temperature multiple-effect evaporator group and the steam condensed water out of a cooler are collected to a condensed water tank by use of a condensation header and then fed into a boiler water supply system by use of a condensed water pump to be recycled; a thickened liquid generated by performing multiple-effect evaporation on the salt-containing wastewater is recycled into a thickened liquid recovery tank and then fed into a wet boiler flue gas desulphurization system used as a desulfurizing agent for desulphurization.

The invention relates to a high-temperature seawater desalting and distillation device and method. The device comprises a preheater, a multi-effect evaporator, respective-effect gas-liquid separators and a circulation pump. A vertical evaporator is adopted, the steam is heated in the equipment initial operating stage for gradually preheating calcium removed seawater stage by stage, secondary steam generated in the evaporation process is used for preheating the seawater, condensed water generated by the respective-effect gas-liquid separators is used for initial seawater preheating, the condensed water after the secondary steam seawater preheating is used for preheating the seawater after the heat exchange by condensed water generated by the separators, the heat efficiency is improved, the heating steam heat loss is reduced, the self afterheat of a system is sufficiently utilized, and the recovery rate of fresh water is improved. The device and the method are applicable to calcium removed or calcium and magnesium removed seawater, the heating temperature can be 40 to 170 DEG C, the heating temperature range is wide, the scale accumulation limitation is avoided, the total dissolved solids (TDS) of the desalted strong brine can be 50000 to 250000 mg/L, and the recovery rate of the fresh water is 40 to 75 percent. High-concentration, high-temperature and high-quality raw materials are provided for factory salt preparation, and the firm foundation is laid for the zero discharge of the seawater desalting.

The invention discloses a method for treating riboflavin fermentation waste water, which comprises the following steps of: concentrating and drying the waste water after extracting riboflavin fermentation liquor by using a multi-effect evaporation system; drying concentrated dense size to obtain a large amount of solid protein feed; and putting condensed condensate water in a multi-effect evaporator into a biochemical system, and treating the condensate water by adopting an 'anaerobic upflow anaerobic sludge blanket (UASB), anaerobic/oxic (A/O) and contact oxidization decoloration' method. The method changes the conventional sewage treatment mode, effectively separates solid matters in riboflavin production waste water, reduces the sewage treatment difficulty, and solves sewage biochemical oxygen demand/chemical oxygen demand (B/C) values, thereby ensuring that the sewage can be biochemically degraded more easily and the waste water can be discharged up to standard. Simultaneously, the solid protein feed is recovered, and the up-to-standard waste water is recycled for blending, fermentation water replenishing, extracting working section and/or greening and the like, thereby saving water resources. The biogas generated by anaerobic treatment is collected for comprehensive utilization, thereby saving energy sources and realizing comprehensive utilization of resources.

Comprehensive utilization technology of viscose fiber acid wastewater includes the steps: firstly, filtering the viscose fiber acid wastewater by a filter, removing suspended matters in the wastewater and treating filtered solution in a next step; secondly, leading the filtered solution into a reverse osmosis system to obtain membrane concentrated solution and membrane permeate liquid, directly reusing the membrane permeate liquid as process water and treating the membrane concentrated solution in a step C; finally, leading the membrane concentrated solution obtained by reverse osmosis treatment into a multi-effect evaporator for concentration, feeding the membrane concentrated solution into a crystallizing tank for crystallization to obtain sodium sulfate crystals. Crystallized mother liquid is sulfuric acid, contains sodium sulfate and zinc sulfate and can be directly reused in a coagulating bath. By membrane combination technology, the sulfuric acid, the zinc sulfate, the sodium sulfate and the water are recycled, the problems of zinc discharge and solid waste are solved, and resources are comprehensively utilized.

The invention discloses a process for refining crude salt. A salt-leaching step comprises the following steps: sending crude salt to a salt leaching device, a ball mill, a primary salt slurry barrel, a thickener and a primary centrifuge in sequence; then sending salt slurry separated from the primary centrifuge to a secondary salt slurry barrel, a classificator and an immediate washing barrel for washing and thickening; then using condensate water to wash the salt slurry after entering the secondary centrifuge so as to remove bittern, thereby obtaining qualified leached salt; a crude bittern treatment step comprises the following steps: mixing leaching crude bittern in the salt leaching step in a crude bittern pool, and subsequently sending to a calcium-magnesium reactor so as to remove Ca<2+> and Mg<2+>; then entering a clarifying tank for clarifying; after increasing the temperature of the clarified clear liquor by a bittern heater, sending portion of clarified clear liquor to a refining bittern barrel for vacuum salt manufacturing with portion of clarified clear liquor for salt leaching use; and a vacuum salt manufacturing step comprises the following steps: sending refined salt water in the refining bittern barrel to a multi-effect evaporator for evaporating; finally discharging separated solid salt to the salt slurry barrel, the salt slurry thickener and the vacuum centrifuge, thereby obtaining leached salt. The method reduces the crude salt loss and lowers the content of SO4<2-> in the leached salt.

A system and method for desalination of seawater W having an original water salinity and an original water concentration of scale forming components, the system comprising: a pre-treatment sub-system for at least partial removal from said water W of said scale forming components, producing thereby a pre-treated feed water having a first concentration of scale forming components lower than said original concentration of scale forming components; a forward feed flow multi-effect evaporator adapted for distillation of said pre-treated feed water, producing thereby main desalted water product WM having a desalted water salinity lower than said water salinity, and main brine having a salt concentration of approximately 10%; a concentrator adapted for receiving therein said main brine and concentrating it, producing thereby more concentrated brine with an increased salt concentration of approximately 20%-22%, and releasing a first additional desalted water product W1; and a crystallizer for receiving said more concentrated brine, adapted for crystallization thereof to obtain at least solid salt products and releasing a second additional desalted water product W2.

The invention discloses a waste gas recovery method and device in waste heat utilizing technique domain, which is characterized by the following: generating waste gas from amidon by-product drying process; leading in maize milk condensing device; proceeding condensed process fro the maize milk; setting the waste gas recovery device as tube bundle dryer, maize milk condensing device and waste gas outlet on the tube bundle dryer; setting the maize milk condensing device as multi-effect evaporator; setting the evaporator as tube pass and shell pass; arranging washing gas tower between the tube bundle dryer and the maize milk condensing device. This invention possesses lower energy consumption, which can save energy from the maize milk condensing production.

The invention discloses a high-concentration organic waste water evaporating and concentration processing method. A combination of a multi-effect evaporator and a fractionating tower is used for efficient separation of organic matter and water. Feeding waste water is preheated through countercurrent flow and efficient utilization of heat is achieved. The method is especially suitable for waste water which has high organic concentration (COD is larger than or equal to 20000mg/L) and complicated components and is hard to degrade biochemically. Organic waste water is deposited, filtered, preheated and evaporated in a multi-effect mode and undergoes fractional distillation, so that the organic matter concentration of obtained water is quite low (COD is smaller than or equal to 1000mg/L). Compared with traditional multi-effect evaporation and concentration, the efficient utilization of heat is achieved, the organic matter concentration of distilling water outlet is obviously reduced, and therefore the loads for biologically processing follow-up distilled water are relieved and the follow-up procedure of processing the distilled water is avoided. Emission reaching the standard is directly performed.

Disclosed is an evaporative desalination device of multi-stage and multi-effect using solar heat constructed in multi stage and multi effect as a desalination device that is capable of not only increasing fresh water output but also resolving a problem of conventional desalination device having series structure as well, through constructing: a multi stage vapor generator that generates vapor by passing a hot water supply pipe successively through a plurality of vapor generators to evaporate sea water inside thereof; a multi effect vapor generator that uses vapor in the respective vapor generators as heat source and forms a plurality of evaporator groups; and a discharge unit that condenses vapor in the multi effect generator by sea water to discharge fresh water in liquid state, and returns and supplies portions of discharged sea water to the multi stage vapor generator and the multi effect evaporator.

The invention provides a liquid level online measuring method based on the magnetic buoyancy. Through calibrating the corresponding volume of the liquid level in a multiple effect evaporator, the function relationship between the volume and the liquid level is constructed, and the function is inputted into a computer, thereby measuring the evaporation liquid volume; and the density function Rho and the temperature correction coefficient k of the condensed liquid evaporation process are measured, and the relevant parameters are inputted in to the computer, thereby measuring the mass of the evaporation liquid. The invention provides a liquid level measuring method based on the principle of magnetic floater, the aim is to solve the technical problem of condensed liquid measurement in the vacuum boiling state, to achieve the real automatic control of the condensed process, to reduce the condensed process differences of traditional Chinese medicine between different batches, and to provide a new technology for improving the production quality stability and the modernization of the traditional Chinese medicine. The invention has the advantages of reasonable design, simple preparation of the multiple effect evaporator, and low cost.

The invention relates to an energy-saving fine chemical wastewater treatment system and treatment method. The system comprises a forward osmosis membrane concentration device and a multi-effect evaporator, wherein the forward osmosis membrane concentration device comprises FO membrane closed exchange boxes, a drawn liquid recycling device and a clear water recovery device, at least one stage of FO membrane closed exchange box is arranged, the drawn liquid recycling device is connected with each stage of the FO membrane closed exchange box through an electric valve respectively, the clear water recovery device is connected with the drawn liquid recycling device, and all the stages of FO membrane closed exchange boxes are sequentially connected through liquid discharge electric valves and connected with a mother liquid incineration furnace through overtaking electric valves. The method is designed against high osmotic pressure property of fine chemical wastewater, and by preparing drawn liquid with relatively high colligative property and utilizing the osmotic pressure difference caused by differences in colligative property of a solution, the fine chemical wastewater can be efficiently concentrated, water resources can be simultaneously recycled, and electric energy is produced; and the operation process realizes automatic interlocking control, and the operation way can be adjusted according to different water inlet conditions.

The invention provides a high-efficiency and energy-saving multi-effect evaporator system which comprises a multi-effect evaporation set, a condensing tank and a circulation pool, wherein the multiple-effect evaporation set comprises series-connected evaporators with more than two effects, each evaporator is provided with a feeding hole, a discharging hole, a steam inlet and a steam outlet; the feeding hole of the first-effect evaporator is a general feeding hole of the evaporation set, a steam inlet of the first-effect evaporator is a general steam inlet of the evaporation set, a discharging hole of a final-effect evaporator is a total discharging hole of the evaporation set, a steam outlet of the final-effect evaporator is a general steam outlet of the evaporation set, a discharging hole of the former-effect evaporator is communicated with a feeding hole of a second-effect next-effect evaporator, a steam outlet of the former-effect evaporator is communicated with a steam inlet of the next-effect evaporator, the condensing tank is communicated with the general steam outlet, and the circulating pool is communicated with the condensing tank. The multi-effect evaporator system disclosed by the invention is high in efficiency, energy-saving, and good in adaptability. The high-efficiency and energy-saving multi-effect evaporator system can be used for treating high-salt content wastewater.

The invention relates to a wastewater treatment method, in particular to a pretreatment method for epoxy resin desalinization wastewater. The pretreatment method comprises the following steps of: storing desalinization wastewater in a wastewater storage tank, naturally settling for 1 day to precipitate epoxy resin with larger particle size, discharging epoxy resin precipitate at the bottom of the wastewater storage tank, pumping supernatant to a reaction kettle, adjusting the pH value to 11-13, heating, stirring for 1-3h while maintaining the temperature at 70-120 DEG C, introducing steam for at least 30min, condensing and recovering volatile gas with a condenser, pumping reaction liquid to a settling tank, carrying out plate-frame pressure filtration to remove gelatinized epoxy resin, and pumping filtrate to a multi-effect evaporator for concentration by evaporation. By adopting the process provided by the invention, epoxy resin, epoxy chloropropane, methyl isobutyl ketone and other impurities in the desalinization wastewater are effectively removed, the wastewater is sufficiently purified before entering the multi-effect evaporator, and the problems that the multi-effect evaporator pipeline is easy to block and the distilled water is high in COD (Chemical Oxygen Demand) are solved.

The invention provides a system to prepare glycol, which comprises: an oxirane reaction system with a tube-row fixed bed reactor with the tube size within 40~50mm, an oxirane hydration reaction system, a glycol evaporation system with a multi-effect evaporator system in series and a heat exchanger with low-pressure steam as heat source, and a vacuum dewatering system with a pre-heater arranged in front of the tower to heat the feeding solution to or more than its bubble point temperature; Wherein, the reboiler in the evaporation system has tube plate as dual-face composite structure steel plate, basic material layer as carbon steel, tube side composite layer as Monel alloy, and shell side composite layer as stainless steel. This invention takes small land, needs low investment, solves effectively the corrosion protection and coking problems for device, and has well economic benefit.