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48 results about "Titanium(II) oxide" patented technology

Titanium(II) oxide (TiO) is an inorganic chemical compound of titanium and oxygen. It can be prepared from titanium dioxide and titanium metal at 1500 °C. It is non-stoichiometric in a range TiO0.7 to TiO1.3 and this is caused by vacancies of either Ti or O in the defect rock salt structure. In pure TiO 15% of both Ti and O sites are vacant. Careful annealing can cause ordering of the vacancies producing a monoclinic form which has 5 TiO units in the primitive cell that exhibits lower resistivity. A high temperature form with titanium atoms with trigonal prismatic coordination is also known. Acid solutions of TiO are stable for a short time then decompose to give hydrogen...

Titanium oxide/tungsten oxide nano-composite film on surface of metallic titanium, preparation and application

The invention relates to a titanium oxide / tungsten oxide nano-composite film on the surface of metallic titanium, preparation and an application. The metallic titanium is cleaned and etched, then the metallic titanium is impregnated in an oxidation liquid containing peroxotungstic acid sol and hydrogen peroxide and is kept for a period of time at a certain temperature, a titanic acid and peroxotungstic acid containing nano-film formed through crystal in-situ growth and deposition is obtained, and finally, the titanium oxide / tungsten oxide nano-composite film on the surface of the metallic titanium is obtained through calcination; the film mainly comprises a titanium dioxide and tungsten trioxide compound with a nanobelt structure, the nanobelt width is in a range from 10 nm to 150 nm, and the length is in a range from 0.5 mu m to 20 mu m; the mass percentage of titanium oxide is in a range from 1% to 99.5%, and titanium oxide mainly adopts a rutile or anatase crystalline phase; the mass percentage of tungsten oxide is in a range from 0.5%-99%, and tungsten oxide mainly adopts a hexagonal or monoclinic crystal phase. Compared with the prior art, the preparation is simple and easy and is suitable for large-scale industrial production; the prepared titanic oxide film has important application value in the related fields of photoelectrocatalysis, metal corrosion prevention, electrochemical sensing and the like.
Owner:SHANGHAI JIAO TONG UNIV

Preparation method of lithium titanate material

The invention belongs to a lithium battery material, and concretely relates to a preparation method of a lithium titanate material. The method comprises the following steps: 1, adding tetrabutyl titanate into anhydrous ethanol, and uniformly stirring to form a titanium alcohol solution; 2, adding lithium acetate into the titanium alcohol solution, and uniformly stirring to form a mixed solution; 3, adding titanium monoxide powder into the mixed solution, and carrying out low-temperature ultrasonic treatment for 1-2 h to obtain a suspension; 4, spraying the suspension into a constant-temperature reaction kettle, sealing, depositing, decompressing and cooling to obtain coated titanium monoxide particles; and 5, putting the coated titanium monoxide particles into the sealed reaction kettle, carrying out constant-pressure standing for 1-3 h, then introducing water vapor, carrying out a sealed pressurization reaction for 2-3 h, relieving the pressure, and carrying out sealed sintering so asto obtain lithium titanate particles. The problem that an existing lithium titanate material is poor in electrical conductivity is solved; and titanium monoxide is used as an inner core, and lithiumtitanate is used as a surface coating layer, so it is guaranteed that the prepared material has oxygen deficiency, the mobility of electrons is improved, and the electrical conductivity is improved.
Owner:江苏众钠能源科技有限公司

Particulate titanium oxide, method and apparatus for manufacturing the same, and treatment methods using such titanium oxide

Titanium oxide grains of large specific area and high crystallinity with reduced internal defects, whose high photocatalytic activity as a photocatalyst is promising; and titanium oxide grains which even when heated at high temperature, exhibits low tendency of transformation to rutile crystal structure and exhibits low rate of sintering. As titanium oxide grains for composing a photocatalyst, use is made of those of the shape of a boxy polyhedron. The polyhedron constituting the titanium oxide grains is composed of one or more titanium oxide single-crystal polyhedrons. The crystallinity can be enhanced by causing the flatness ratio of single-crystal polyhedrons to fall within the range of 0.33 to 3.0. It is preferred that the polyhedron be a hexa to decahedron. The rutile transformation ratio R (700 to 24) is to be 7.5% or less while the rutile transformation ratio R (500 to 24) is to be 2.0% or less. Titanium oxide grains of the above configuration are produced through a process comprising feeding titanium tetrachloride vapor and oxygen into a synthetic tube of quartz glass and heating them from the exterior of the synthetic tube by means of an oxyhydrogen flame burner so as to effect thermal oxidation.
Owner:FUJIKURA LTD

Solar cell, production method and photovoltaic module

The invention provides a solar cell, a production method and a photovoltaic module, and relates to the technical field of solar photovoltaics. The solar cell comprises a silicon substrate, a first titanium oxide layer, a second titanium oxide layer, a first electrode and a second electrode, wherein the first titanium oxide layer has electron selectivity, and the second titanium oxide layer has hole selectivity; the first electrode is located on the first titanium oxide layer; the second electrode is positioned on the second titanium dioxide layer; the first titanium oxide layer and the secondtitanium oxide layer are respectively positioned on a light-facing surface and a backlight surface of the silicon substrate; or the first titanium oxide layer and the second titanium oxide layer are respectively positioned in a first region and a second region of the backlight surface of the silicon substrate. The production process of the first titanium oxide layer and the second titanium oxide layer is less than or equal to 600 DEG C, the temperature is low, impurities are reduced, the service life of minority carriers is long, the cell structure is simplified, and the process is simplified.The first titanium oxide layer and the second titanium oxide layer can avoid direct contact between the silicon substrate and the electrodes, and the recombination rate is greatly reduced.
Owner:LONGI SOLAR TECH (TAIZHOU) CO LTD

Preparation method for self-active lithium titanate material

ActiveCN111137916AImprove conductivityRealization of electron-hole structureAlkali titanatesCell electrodesAlcoholEthylic acid
The invention discloses a preparation method for a self-active lithium titanate material. The preparation method comprises the following steps: step 1, adding lithium acetate into absolute ethyl alcohol, and carrying out uniform stirring for 1-3 hours so as to obtain a lithium alcohol solution; step 2, adding titanium monoxide powder into the lithium alcohol solution, and carrying out low-temperature ultrasonic treatment for 2-4 hours so as to obtain a mixed turbid liquid; step 3, uniformly spraying the mixed turbid liquid into a sealed reaction kettle, carrying out standing for 1-2 hours at aconstant temperature, and carrying out decompressing and cooling so as to obtain coated titanium monoxide particles; step 4, adding the coated titanium monoxide particles into a mold, and carrying out a constant-temperature and constant-pressure reaction for 2-4 hours so as to obtain a primary lithium titanate plate; and step 5, soaking the primary lithium titanate plate into tetrabutyl titanate,carrying out low-temperature ultrasonic treatment for 3-5 hours, then carrying out an extrusion reaction for 2-4 hours in a humid environment, and carrying out sintering so as to obtain the self-active lithium titanate material. According to the invention, the problem of poor conductivity of lithium titanate is solved; and titanium monoxide is used as an inner core, and lithium titanate is endowed with oxygen deficiency by utilizing the oxygen deficiency of the titanium monoxide, so an electron-hole structure of the lithium titanate is realized, and the overall conductivity and activity are greatly improved.
Owner:江苏众钠能源科技有限公司

Preparation method of efficient titanium-based photocatalyst

The invention belongs to the field of photocatalysis, and particularly relates to a preparation method of a high-efficiency titanium-based photocatalyst, which comprises the following steps: step 1, sequentially putting a base material into distilled water and anhydrous ethanol for ultrasonic cleaning for 20-30min, and performing drying to obtain a clean base material; 2, adding polyvinyl alcoholinto distilled water, stirring the substances uniformly to obtain a polyvinyl alcohol solution, then dipping the base material into the polyvinyl alcohol solution, then taking base material out, and performing drying to obtain a polyvinyl alcohol film; 3, spraying nano titanium monoxide powder on the surface of the polyvinyl alcohol film, and then spraying n-butyl titanate on the surface to obtaina multi-film base material; and 4, putting the multi-film base material into a sintering kettle, and carrying out sealed sintering for 2-5h to obtain the titanium-based photocatalytic film. The method provided by the invention solves the problem of low electron yield of existing nano titanium dioxide, utilizes the oxygen deficiency of titanium monoxide to form a multi-titanium structure with n-butyl titanate converted titanium dioxide, enhances the activity of the surface titanium dioxide, and effectively improves the photocatalytic efficiency.
Owner:绍兴市梓昂新材料有限公司

Particulate titanium oxide, method and apparatus for manufacturing the same, and treatment methods using such titanium oxide

Titanium oxide grains of large specific area and high crystallinity with reduced internal defects, whose high photocatalytic activity as a photocatalyst is promising; and titanium oxide grains which even when heated at high temperature, exhibits low tendency of transformation to rutile crystal structure and exhibits low rate of sintering. As titanium oxide grains for composing a photocatalyst, use is made of those of the shape of a boxy polyhedron. The polyhedron constituting the titanium oxide grains is composed of one or more titanium oxide single-crystal polyhedrons. The crystallinity can be enhanced by causing the flatness ratio of single-crystal polyhedrons to fall within the range of 0.33 to 3.0. It is preferred that the polyhedron be a hexa to decahedron. The rutile transformation ratio R (700 to 24) is to be 7.5% or less while the rutile transformation ratio R (500 to 24) is to be 2.0% or less. Titanium oxide grains of the above configuration are produced through a process comprising feeding titanium tetrachloride vapor and oxygen into a synthetic tube of quartz glass and heating them from the exterior of the synthetic tube by means of an oxyhydrogen flame burner so as to effect thermal oxidation.
Owner:THE FUJIKURA CABLE WORKS LTD

A kind of preparation method of lithium titanate material

The invention belongs to lithium battery materials, and specifically relates to a method for preparing a lithium titanate material, comprising the following steps: step 1, adding tetrabutyl titanate into absolute ethanol and stirring evenly to form a titanium alcohol solution; step 2, adding acetic acid Lithium is added to the titanic acid solution and stirred evenly to form a mixed solution; step 3, the titanium monoxide powder is added to the mixed solution by low-temperature ultrasound for 1-2 h to obtain a suspension; step 4, the suspension is sprayed to the constant temperature reaction kettle In the process, the coated titanium monoxide particles are obtained after sealing deposition and pressure relief cooling; step 5, the coated titanium monoxide particles are placed in the sealed reaction kettle for 1-3 hours under constant pressure, and then water vapor is introduced to carry out the sealed and pressurized reaction 2- 3h, after the pressure was released, it was sealed and sintered to obtain lithium titanate particles. The invention solves the problem of poor electrical conductivity of the existing lithium titanate material, uses titanium monoxide as the inner core, and uses lithium titanate as the surface coating layer to ensure that the prepared material has oxygen deficiency, improves the mobility of electrons, and thus improves the the conductivity.
Owner:江苏众钠能源科技有限公司
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