The invention relates to a heavy 
metal collecting agent and a 
thallium-removal method used for 
sintering desulfurization waste water. The method is divided into two stages, wherein the first-stage treatment comprises the steps of adjusting the 
thallium-containing waste water to be alkaline, and adding coagulant; the second-stage treatment comprises the steps of adding agentia and coagulant to supernatant obtained after 
solid-liquid separation of the first-stage treatment, and 
effluent is drained outward directly after being subjected to press filtering. The agentia is prepared from, by weight, 20-30% of 
urea, 1-3% of linear chain 
small molecule amine substances, 4-9% of 
carbon disulfide, 0.4-0.7% of 
epoxy chloropropane, 0.5-0.8% of surfactant and the 
balance water. A preparation method comprises the steps of adding water for being mixed with 
urea, amine substances and 
epoxy chloropropane, stirring the mixture for a certain time at the 
room temperature, then dropwise adding 
carbon disulfide, continuing with the reaction, after a period of time passes, raising the temperature, continuing stirring, after the reaction is completed, lowering the temperature to the 
room temperature, adding surfactant, stirring the mixture uniformly, and obtaining the product. According to the heavy 
metal collecting agent and the 
thallium-removal method used for 
sintering the desulfurization waste water, the agentia is added to the thallium-containing waste water to be treated, and 
metal complex is formed after the mixture is stirred sufficiently. By means of the process, thallium and other heavy metal ions in the 
sintering desulfurization waste water can be effectively removed, environmental 
pollution is avoided, and waste 
water treatment cost is effectively lowered.