The invention provides magnetic COF-TpPa for enriching amide pesticides and a preparation method and application of the magnetic COF-TpPa and belongs to the technical field of adsorption materials. The preparation method provided by the invention comprises the following steps: (1) mixing 2,4,6-trihydroxy benzene-1,3,5-trioxin, amination magnetic beads and ethanol, and carrying out a first aldehydeamine condensation reaction so as to obtain aldehyde magnetic beads; and (2) putting a solution of p-phenylenediamine into a dispersion liquid of the aldehyde magnetic beads, further adding a solution of 2,4,6-trihydroxy benzene-1,3,5-trioxin, and carrying out a second aldehyde amine condensation reaction, thereby obtaining magnetic COF-TpPa for enriching amide pesticides. The magnetic COF-TpPa which is prepared by using the preparation method provided by the invention has excellent adsorption upon amide pesticides (prochloraz and tolfenpyrad), is good in stability, has superparamagnetism andis easy to separate, in addition, the preparation method is simple to operate, and reaction conditions are gentle and controllable.