The present application relates to the field of organic materials, in particular to a black
polyimide film and a preparation method thereof.The black
polyimide film provided by the present application has a
polyimide with a structure shown in formula (L).In the preparation method provided by the present application, an
aniline oligomer diamine shown in formula (II) is used, wherein each bridging
nitrogen atom is coupled with a protective group, such as benzyloxy carbonyl or tert-butyloxy carbonyl; the above-mentioned
diamine monomer is homopolymerized or copolymerized with a
diamine monomer shown in formula (III) and a dianhydride
monomer to form a resin solution; then, a polyimide /
polyamic acid film is prepared through a film forming process; and then, a deprotection
group treatment is performed, so that an intrinsic black polyimide film is obtained.The
polymer prepared by the present application has excellent
solubility, and after the deprotection, the material exhibits uniform black properties, excellent
solvent resistance and mechanical properties, thereby solving the contradiction between the
processing performance and the
solvent resistance and mechanical properties.