The invention discloses positive paste containing secondary-layer 
graphene and a preparation method of the positive paste. The positive paste comprises a main material, a 
solvent and an additive, wherein the content of the main material accounts for 56-59wt%, the content of NMP accounts for 21-24wt%, the content of PVDF accounts for 2-3.5wt%, the content of SP accounts for 15-17wt%, the content ofthe secondary-layer 
graphene accounts for 0.7-1.2wt%, the secondary-layer 
graphene comprise multi-layer sheet-shaped graphene and diamonds, the diamonds are arranged between adjacent two 
layers of the multi-layer sheet-shaped graphene and are in one-to-one correspondence to carbon atoms of the multi-layer sheet-shaped graphene, and the weight ratio of the secondary-layer graphene and the diamondsis (18-19):1. The positive paste is reasonable in formula and excellent in heat 
conductivity, the secondary-layer graphene is a new material of 3-5 
layers of sheet-shaped graphene doped with the diamonds, the added diamonds are spherical carbon, so that adjacent 
layers of the multi-layer sheet-shaped graphene are conducted, and the electrical 
conductivity of the material is improved; and therefore, the 
thermal conductivity is improved under the condition that other structures of a battery are not changed, heat generated by power generation is timely dissipated, and the 
energy consumption is effectively reduced when the battery is discharged with a relatively large current.