The invention discloses a long-acting melt-blown polypropylene composite electret material for mask melt-blown cloth and a preparation method of the long-acting melt-blown polypropylene composite electret material. The long-acting melt-blown polypropylene composite electret material comprises the following components in parts by weight: 100 parts of polypropylene resin, 0.1 to 10 parts of a fluorosilicone polymer, 0.01 to 2 parts of an inorganic charge enhancer, 0.1 to 2 parts of a lubricant, and 0.01 to 0.3 part of an antioxidant, wherein the fluorosilicone polymer is fluorine-containing polysiloxane taking a silicon-oxygen bond as a main chain and fluoroalkyl as a side chain. In the long-acting melt-blown polypropylene composite electret material for mask melt-blown cloth, a silicon-oxygen main chain of the fluorosilicone polymer is smooth, increase of the charge injection depth can be facilitated, a fluoroalkyl side chain promotes charge capture, meanwhile, dipole directional arrangement is generated, a main chain can be masked, a cloth cover is endowed with good hydrophobicity, the material has a good electret effect, and the long-term effect of the material is effectively improved. Moreover, the fluorosilicone polymer is low in melting point and is uniformly dispersed, so that the melt-blown polypropylene composite electret material is relatively simple to process and form.